2-hetaroylcyclohexane-1,3-diones

ABSTRACT

Hetaroyl derivatives of the formula I ##STR1## where the substituents have the following meanings: L and M hydrogen, C 1  -C 6  -alkyl, C 2  -C 6  -alkenyl, C 2  -C 6  -alkynyl, C 1  -C 4  -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C 1  -C 4  -alkoxy; halogen, cyano, nitro; 
     X oxygen or sulfur which can be substituted by one or two oxygens; 
     n zero, one, two; 
     Q,R 1 ,R 2 ,R 3  and R 4  have the meanings given in claim 1, 
     processes for preparing the hetaroyl derivatives, compositions which contain them and the use of these derivatives or compositions containing them for controlling weeds are described.

This application is a 371 of PCT/EP97/00802 filed Feb. 20, 1997.

The present invention-relates to novel hetaroyl derivatives having herbicidal activity, processes for preparing the hetaroyl derivatives, compositions which contain them and the use of these derivatives or compositions containing them for controlling weeds.

The literature discloses herbicidally active 2-hetaroylcylohexadiones, for example in WO 948988, WO 9404524 and EP 283261.

The herbicidal properties of the known compounds and the tolerability to crop plants can only be satisfactory, however, to a limited extent.

It is an object of the present invention to find novel 2-hetaroylcyclohexanediones having improved properties.

We have found that this object is achieved by the hetaroyl derivatives of the formula I ##STR2## where the substituents have the following meanings: L and M hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen, cyano, nitro;

X oxygen or sulfur which can be substituted by one or two oxygens;

n zero, one, two;

R¹ hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C1-C₄ -alkoxy [sic], it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen;

phenyl which can be monosubstituted or polysubstituted by the following groups: C₁ -C₄ -alkyl, hydrogen, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, nitro, cyano, C₁ -C₄ -alkyloxycarbonyl;

R² hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen;

phenyl which can be monosubstituted or polysubstituted by the following groups: C₁ -C₄ -alkyl, hydrogen, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, nitro, cyano, C₁ -C₄ -alkyloxycarbonyl; R³ and R² can form a bond;

R³ hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen;

phenyl which can be monosubstituted or polysubstituted by the following groups: C₁ -C₄ -alkyl, hydrogen, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, nitro, cyano, C₁ -C₄ -alkyloxycarbonyl; R³ and R² can form a bond;

R⁴ hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen;

phenyl which can be monosubstituted or polysubstituted by the following groups: C₁ -C₄ -alkyl, hydrogen, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, nitro, cyano, C₁ -C₄ -alkyloxycarbonyl;

Q a cyclohexane-1,3-dione ring, linked in the 2-position, of the formula II ##STR3## where the substituents have the following meanings: R⁵, R⁶ and R¹⁰ hydrogen, C₁ -C₄ -alkyl;

R⁷ hydrogen, C₁ -C₄ -alkyl, C₃ -C₄ -cycloalkyl, it being possible for these groups, if desired, to carry one to three of the following substituents: halogen, C₁ -C₄ -thioalkyl or C₁ -C₄ -alkoxy; or

C₁ -C₄ -alkoxy; C₁ -C₆ -alkoxyalkyl, tetrahydropyran-3-yl, tetrahydropyran-4-yl; or

R⁷ and R⁹ can together form a bond or a three- to six-membered carbocyclic ring;

R⁸ hydrogen, C₁ -C₄ -alkyl;

R⁹ hydrogen, C₁ -C₄ -alkyl or a group COOR¹¹ ;

R¹¹ C₁ -C₄ -alkyl;

and agriculturally utilizable salts.

Compounds of the formula I are obtained by reacting compounds of the formula II with a benzoic acid derivative of the formula III and rearranging them to give hetaroyl derivatives of the formula I. ##STR4##

In the above scheme 1, T in the formulae mentioned has the meaning halogen or OH and L, M, X, R¹, R², R³, R⁴ and n have the meanings given above.

The first step of the reaction sequence, the acylation, is carried out in a generally known manner, eg. by addition of an acid chloride of the formula III (T═Cl) or of a carboxylic acid III T(═OH) activated, for example, with DCC (dicyclocarbodiimides or similar agents known from the literature, eg. triphenylphosphine/DEAD=diethyl azodicarboxylate, 2-pyridine disulfide/triphenylphosphine to the solution or suspension of a cyclohexanedione II, if appropriate in the presence of an auxiliary base. The reactants and the auxiliary base are in this case expediently employed in equimolar amounts. A small excess, eg. from 1.2 to 1.5 mol equivalents, based on II, of the auxiliary base can be advantageous under certain circumstances.

Suitable auxiliary bases are tertiary alkylamines, pyridine or alkali metal carbonates. The solvents used can be, for example, methylene chloride, dioxane, diethyl ether, toluene, acetonitrile or ethyl acetate.

During the addition of the acid chloride, the reaction mixture is preferably cooled to from 0 to 10° C., and it is then stirred at from 20 to 100° C., in particular 25 to 50° C., until the reaction is complete. Working-up is carried out in the customary manner, eg. the reaction mixture is poured into water and the useful product is extracted, eg. with methylene chloride. After drying of the organic phase and removal of the solvent, the crude enol ester can be employed for the rearrangement without further purification. Preparation examples for benzoyl enol esters of cyclohexane-1,3-diones are found, for example, in EP-A 186118 or U.S. Pat. No. 4,780,127.

The rearrangement of the enol esters to the compounds of the formula Ia-Ie is expediently carried out at from 20 to 40° C. in a solvent and in the presence of an auxiliary base, and with the aid of a cyano compound as a catalyst.

The solvents used can be, for example, acetonitrile, methylene chloride, 1,2-dichloroethane, ethyl acetate or toluene. A preferred solvent is acetonitrile. Suitable auxiliary bases are tertiary alkylamines, pyridine or alkali metal carbonates, which are preferably employed in an equimolar amount or up to a four-fold excess, based on the benzoyl enol ester. A preferred auxiliary base is triethylamine in twice the amount.

Suitable catalysts are potassium cyanide, acetone cyanohydrin and trimethylsilyl cyanide, preferably in an amount of from 1 to 50 mol percent, based on the enol ester. Acetone cyanohydrin is preferably added, eg. in an amount of from 5 to 15, in particular 10, mol percent. Examples of cyanide-catalyzed rearrangement of enol esters are found, for example, in EP-A 186118 or U.S. Pat. No. 4,780,127.

Working-up is carried out in a manner known per se, eg. the reaction mixture is acidified with dilute mineral acids such as 5% strength hydrochloric acid or sulfuric acid and extracted with an organic solvent such as methylene chloride or ethyl acetate. For purification, the extract is extracted with cold 5 to 10% strength alkali metal carbonate solution, the final product passing into the aqueous phase. By acidifying the aqueous solution, the product of the formula Ia-Ie is precipitated or again extracted with methylene chloride or ethyl acetate, dried and then freed from the solvent.

The 1,3-diketones of the formula II used as starting material are known and can be prepared by methods known per se, such as are described, for example, in EP-A 71707, EP-A 142741, EP-A 243313, U.S. Pat. No. 4,249,937 and WO 92/13821. Cyclohexanedione and dimedone are commercially available compounds.

Benzoic acid derivatives of the formula III can be prepared in the following manner:

Benzoyl halides such as, for example, benzoyl chlorides of the formula III (T═Cl) are prepared in a manner known per se by reaction of the benzoic acids of the formula III (T═OH) with thionyl chloride.

The benzoic acids of the formula III (T═OH) can be prepared from the corresponding esters of the formula III (T=C₁ -C₄ -alkoxy) in a known manner by acidic or basic hydrolysis.

The intermediates of the formula III can be prepared starting from compounds which are in some cases known from the literature, such as substituted phenolcarboxylic acids IV or thiocarboxylic acids V. Unknown compounds IV or V can be synthesized by use of reactions known from the literature (ref.: Houben Weyl, Methoden der Organischen Chemie [Methods of Organic Chemistry] Volume VI, IX and E11).

Further reaction to give the intermediates of the formula III proceeds via processes known from the literature (eg. Synthesis 1975, 451; J. Org. Chem. 1974, 39-1811; J. Am. Chem. Soc. 1954, 76, 1068; Heterocyclic Compounds, Volume: Multi-Sulfur and Sulfur and Oxygen Five and Six-Membered Heterocycles; J. Org. Chem. 1979, 44, 1977). ##STR5## 2,3-Dihydrobenz-1,4-oxathiin derivatives can then be synthesized, for example, as shown in Scheme 2A, by intermolecular nucleophilic substitution on the aromatic compound (X═O,S; T═OH, C₁ -C₄ -alkoxy) (Lit: J. Heterocycl. Chem. 20, 1983, 867). Routes B and C describe the route specified in the literature to 2-alkoxy-2,3-dihydrobenz-1,4-oxathiin derivatives (Lit: J. Am. Chem. Soc. 76, 1954, 1068; J. Org. Chem. 44, 1979, 1977). Phenols or thiols can be alkylated with alkyl bromides in alkaline solution as shown in scheme 2 in D and E. The reactants and the base are in this case expediently employed in equimolar amounts. An excess of base may be advantageous. Preferred solvents are alcohols such as ethanol or DMF and preferred bases are alkoxides such as, for example, sodium methoxide or, for example, NaH. The reaction can be carried out under normal pressure or at elevated pressure. The preferred pressure range is from 1 to 10 bar. The reaction mixture is preferably stirred at 20-150° C., in particular at 60-80° C. Working-up is carried out, for example, by pouring the reaction mixture onto dilute alkali solution such as sodium hydroxide solution and the useful product can be obtained by extraction with, for example, ethyl acetate, dried and freed from the solvent.

Then, for example, a replacement of Z with potassium methanethiosulfonate in alcoholic solution can be carried out. Preferred solvents are ethanol, methanol and isopropanol. The reaction mixture is in this case preferably stirred at 20-100° C., in particular at 60-80° C.

Working-up is carried out, for example, by addition of water, the useful product being filtered off with suction or extracted by extraction with, for example, methylene chloride and dried.

Cyclization to give the dihydrobenzoxathiin or dihydrobenzodithiin structure is carried out with addition of a Lewis acid in an inert solvent. In this connection, aluminum trichloride is preferred as the Lewis acid and nitromethane or methylene chloride as the inert solvent. The reaction mixture is kept at 20-50° C. Working-up is carried out, for example, by addition of dilute mineral acid such as hydrochloric acid and the useful product is filtered off with suction or extracted by extraction with ether, dried and freed from the solvent.

By oxidation according to methods known from the literature and/or dehydrogenation (Houben Weyl Methoden der Organischen Synthese Volume IV/1a and b), the compounds can be further functionalized.

The benzoic acids of the formula III can also be obtained by reacting the corresponding bromo- or iodo-substituted compounds of the formula XVIII ##STR6## where T is OH, C₁ -C₄ -alkoxy; and

L, M, X, R¹ to R⁴ and n have the meanings described above;

with carbon monoxide and water at elevated pressure in the presence of a palladium, nickel, cobalt or rhodium transition metal catalyst and of a base.

The catalysts nickel, cobalt, rhodium and in particular palladium can be present in metallic form or in the form of customary salts such as in the form of halogen compounds, eg. PdCl₂, RhCl₃.H₂ O, acetates, eg. Pd(OAc)₂, cyanides etc., in the known valency states. Metal complexes with tertiary phosphines, metal alkylcarbonyls, metal carbonyls, eg. CO₂ (CO)₈, Ni(CO)₄, metal carbonyl complexes with tertiary phosphines, eg. (PPh₃)₂ Ni(CO)₂, or transition metal salts complexed with tertiary phosphines can also be present. The last-mentioned embodiment is preferred in particular in the case of palladium as a catalyst. In this connection, the nature of the phosphine ligands is widely variable. For example, they can be represented by the following formulae: ##STR7## where k is the numbers 1, 2, 3 or 4 and the radicals R¹² to R¹⁵ are low-molecular-weight alkyl, eg. C₁ -C₆ -alkyl, aryl, C₁ -C₄ -alkylaryl, eg. benzyl, phenethyl or aryloxy. Aryl is, for example, naphthyl, anthryl and preferably unsubstituted or substituted phenyl, where, with respect to the substituents, attention has to be paid only to their inertness to the carboxylation reaction, otherwise they can be widely varied and include all inert organocarbon radicals such as C₁ -C₆ -alkyl radicals, eg. methyl, carboxyl radicals such as COOH, COOM (M is, for example, an alkali metal, alkaline earth metal or ammonium salt), or organocarbon radicals bonded via oxygen, such as C₁ -C₆ -alkoxy radicals.

The phosphine complexes can be prepared in a manner known per se, eg. as described in the documents mentioned at the outset. For example, customary commercially available metal salts such as PdCl₂ or Pd(OCOCH₃)₂ are used as starting materials and the phosphine, eg. P(C₆ H₅)₃, P(n-C₄ H₉)₃, PCH₃ (C₆ H₅)₂, 1,2-bis(diphenylphosphino)ethane, is added.

The amount of phosphine, based on the transition metal, is customarily from 0 to 20, in particular 0.1 to 10, mol equivalents, particularly preferably 1 to 5 mol equivalents.

The amount of transition metal is not critical. Of course, for reasons of cost rather a small amount, eg. from 0.1 to 10 mol %, in particular 1 to 5 mol %, based on the starting substance II or III, will be used.

For preparation of the benzoic acids III (T═OH), the reaction is carried out with carbon monoxide and at least equimolar amounts of water, based on the starting substances VI. The reaction component water can simultaneously also be used as a solvent, ie. the maximum amount is not critical.

However, depending on the nature of the starting substances and the catalysts used, it may also be advantageous instead of the reaction component to use as a solvent another inert solvent or the base used for the carboxylation.

Suitable inert solvents for carboxylation reactions are customary solvents such as hydrocarbons, eg. toluene, xylene, hexane, pentane, cyclohexane, ethers, eg. methyl tert-butyl ether, tetrahydrofuran, dioxane, dimethoxyethane, substituted amides such as dimethylformamide, persubstituted ureas such as tetra-C₁ -C₄ -alkylureas or nitrites such as benzonitrile or acetonitrile.

In a preferred embodiment of the process, one of the reaction components, in particular the base, is used in an excess, so that no additional solvent is necessary.

Bases suitable for the process are all inert bases which are able to bind hydrogen iodide or hydrogen bromide liberated during the reaction. Examples which may be mentioned here are tertiary amines such as tert-alkylamines, eg. trialkylamines such as triethylamine, cyclic amines such as N-methylpiperidine or N,N'-dimethylpiperazine, pyridine, alkali metal [lacuna] or hydrogencarbonates, or tetraalkyl-substituted urea derivatives such as tetra-C₁ -C₄ -alkylurea, eg. tetramethylurea.

The amount of base is not critical, customarily from 1 to 10, in particular from 1 to 5, mol are used. When simultaneously using the base as a solvent, the amount is generally proportioned such that the reaction components are dissolved, unnecessarily high excesses being avoided for reasons of practicability in order to save costs, to be able to employ small reaction vessels and to guarantee the reaction components maximum contact.

During the reaction, the carbon monoxide pressure is adjusted such that an excess of CO, based on VI, is always present. Preferably, the carbon monoxide pressure at room temperature is from 1 to 250 bar, in particular from 5 to 150 bar, of CO.

The carbonylation is generally carried out continuously or batchwise at from 20 to 250° C., in particular 30 to 150° C. In the case of batchwise operation, carbon monoxide is expediently continuously injected onto the reaction mixture to maintain a constant pressure.

The arylhalogen compounds XVIII used as starting compounds are known or can easily be prepared by suitable combination of known syntheses and according to the reaction sequences described above.

With a view to the intended use of the benzoyl derivatives of the general formula I, suitable substituents are the following radicals:

L, M hydrogen,

C₁ -C₆ -alkyl such as methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, 1-ethylpropyl, hexyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl or 1-ethyl-2-methylpropyl,

in particular methyl, ethyl, 1-methylethyl, 1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl and 1,1-dimethylpropyl;

C₂ -C₆ -alkenyl such as 2-propenyl, 2-butenyl, 3-butenyl, 1-methyl-2-propenyl, 2-methyl-2-propenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, 3-methyl-2-butenyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 1-methyl-3-butenyl, 2-methyl-4-butenyl, 3-methyl-3-butenyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl-2-propenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1-methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1-methyl-3 pentenyl, 2-methyl-3-pentenyl,

3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl, 1,2-dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl, 2,2-dimethyl-3-butenyl, 2,3-dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl, 1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl and ethyl-2-methyl-2-propenyl,

in particular 1-methyl-2-propenyl, 1-methyl-2-butenyl, 1,1-dimethyl-2-propenyl and 1,1-dimethyl-2-butenyl;

C₂ -C₆ -alkynyl such as propargyl, 2-butynyl, 3-butenyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 1-methyl-3-butynyl, 2-methyl-3-butynyl, 1-methyl-2-butynyl, 1,1-dimethyl-2 propynyl, 1-ethyl-2-propynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5-hexynyl, -1-methyl-2-pentynyl, 1-methyl-3-pentynyl, 1-methyl-4-pentynyl, 3-methyl-4-pentynyl, 4-methyl-2-pentynyl, 1,1-dimethyl-2-butynyl, 1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, -2,2-dimethyl-3-butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-butynyl, 2-ethyl-3-butynyl and 1-ethyl-1-methyl-2-propynyl;

C₁ -C₄ -alkoxy such as methoxy, ethoxy, n-propoxy, 1-methylethoxy, n-butoxy, 1-methylpropoxy, 2-methylpropoxy and 1, 1-dimethylethoxy,

in particular C₁ -C₃ -alkoxy such as methoxy, ethoxy, i-propoxy,

it being possible for these groups to be substituted, if desired, by one to five halogen atoms such as fluorine, chlorine, bromine and iodine, preferably fluorine and chlorine or C₁ -C₄ -alkoxy as mentioned above.

Preferred hetaroyl derivatives are those of the formula Ia, ##STR8## where L is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and Q, X, R₁ to R₄ [sic] and n have the meanings given above.

Furthermore preferred hetaroyl derivatives are those of the formula Ib ##STR9## where L is C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and Q, X, R₁ to R₄ [sic] and n have the meanings given above.

Preferred hetaroyl derivatives are also those of the formula I where the radicals L and M are hydrogen, methyl, methoxy, chlorine, cyano, nitro and trifluoromethyl.

Furthermore preferred hetaroyl derivatives are also those of the formula Ic ##STR10## where L is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and Q, R₁ to R₄ and n have the meanings given above.

Preferred hetaroyl derivatives are also those of the formula Id ##STR11## where L is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and Q, R₁, R₄ and n have the meanings given above.

Preferred hetaroyl derivatives are furthermore those of the formula Ie ##STR12## where L is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro, and m is zero, one or two and Q, R₁, R₄ and n have the meanings given above.

Preferred hetaroyl derivatives are also those of the formula If ##STR13## where L is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro, and m is zero, one or two and Q, R₁ to R₄ and n have the meanings given above.

Preferred hetaroyl derivatives of the formula I to If are also those whose substituents consist of a combination of the preferred substituents.

Particularly preferred compounds of the formula I are listed in the following Tables 1-6.

                                      TABLE 1                                      __________________________________________________________________________      ##STR14##                                                                     No. R.sup.5                                                                           R.sup.6                                                                            R.sup.7    R.sup.8                                                                           M   L   X  n                                          __________________________________________________________________________     1.1 H  H   H          H  H   H   O  0                                          1.2 H  H   H          H  H   H   O  2                                          1.3 CH.sub.3                                                                          CH.sub.3                                                                           H          H  H   H   O  0                                          1.4 CH.sub.3                                                                          CH.sub.3                                                                           H          H  H   H   O  2                                          1.5 H  H   H          CH.sub.3                                                                          H   H   O  0                                          1.6 H  H   H          CH.sub.3                                                                          H   H   O  2                                          1.7 H  H   CH.sub.3   CH.sub.3                                                                          H   H   O  0                                          1.8 H  H   CH.sub.3   CH.sub.3                                                                          H   H   O  2                                          1.9 H  H   H          H  CH.sub.3                                                                           H   O  0                                          1.10                                                                               H  H   H          H  CH.sub.3                                                                           H   O  2                                          1.11                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           H   O  0                                          1.12                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           H   O  2                                          1.13                                                                               H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           H   O  0                                          1.14                                                                               H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           H   O  2                                          1.15                                                                               H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           H   O  0                                          1.16                                                                               H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           H   O  2                                          1.17                                                                               H  H   H          H  Cl  H   O  0                                          1.18                                                                               H  H   H          H  Cl  H   O  2                                          1.19                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  H   O  0                                          1.20                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  H   O  2                                          1.21                                                                               H  H   H          CH.sub.3                                                                          Cl  H   O  0                                          1.22                                                                               H  H   H          CH.sub.3                                                                          Cl  H   O  2                                          1.23                                                                               H  H   CH.sub.3   CH.sub.3                                                                          Cl  H   O  0                                          1.24                                                                               H  H   CH.sub.3   CH.sub.3                                                                          Cl  H   O  2                                          1.25                                                                               H  H   H          H  Cl  Cl  O  0                                          1.26                                                                               H  H   H          H  Cl  Cl  O  2                                          1.27                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  Cl  O  0                                          1.28                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  Cl  O  2                                          1.29                                                                               H  H   H          CH.sub.3                                                                          Cl  Cl  O  0                                          1.30                                                                               H  H   H          CH.sub.3                                                                          Cl  Cl  O  2                                          1.31                                                                               H  H   CH.sub.3   CH.sub.3                                                                          Cl  Cl  O  0                                          1.32                                                                               H  H   CH.sub.3   CH.sub.3                                                                          Cl  Cl  O  2                                          1.33                                                                               H  H   H          H  CH.sub.3                                                                           CH.sub.3                                                                           O  0                                          1.34                                                                               H  H   H          H  CH.sub.3                                                                           CH.sub.3                                                                           O  2                                          1.35                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           CH.sub.3                                                                           O  0                                          1.36                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           CH.sub.3                                                                           O  2                                          1.37                                                                               H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  0                                          1.38                                                                               H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  2                                          1.39                                                                               H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  0                                          1.40                                                                               H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  2                                          1.41                                                                               H  H   H          H  NO.sub.2                                                                           H   O  0                                          1.42                                                                               H  H   H          H  NO.sub.2                                                                           H   O  2                                          1.43                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  NO.sub.2                                                                           H   O  0                                          1.44                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  NO.sub.2                                                                           H   O  2                                          1.45                                                                               H  H   H          CH.sub.3                                                                          NO.sub.2                                                                           H   O  0                                          1.46                                                                               H  H   H          CH.sub.3                                                                          NO.sub.2                                                                           H   O  2                                          1.47                                                                               H  H   CH.sub.3   CH.sub.3                                                                          NO.sub.2                                                                           H   O  0                                          1.48                                                                               H  H   CH.sub.3   CH.sub.3                                                                          NO.sub.2                                                                           H   O  2                                          1.49                                                                               H  H   H          H  OCH.sub.3                                                                          H   O  0                                          1.50                                                                               H  H   H          H  OCH.sub.3                                                                          H   O  2                                          1.51                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  OCH.sub.3                                                                          H   O  0                                          1.52                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  OCH.sub.3                                                                          H   O  2                                          1.53                                                                               H  H   H          CH.sub.3                                                                          OCH.sub.3                                                                          H   O  0                                          1.54                                                                               H  H   H          CH.sub.3                                                                          OCH.sub.3                                                                          H   O  2                                          1.55                                                                               H  H   CH.sub.3   CH.sub.3                                                                          OCH.sub.3                                                                          H   O  0                                          1.56                                                                               H  H   CH.sub.3   CH.sub.3                                                                          OCH.sub.3                                                                          H   O  2                                          1.57                                                                               H  H   H          H  H   H   S  0                                          1.58                                                                               H  H   H          H  H   H   S  2                                          1.59                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  H   H   S  0                                          1.60                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  H   H   S  2                                          1.61                                                                               H  H   H          CH.sub.3                                                                          H   H   S  0                                          1.62                                                                               H  H   H          CH.sub.3                                                                          H   H   S  2                                          1.63                                                                               H  H   CH.sub.3   CH.sub.3                                                                          H   H   S  0                                          1.64                                                                               H  H   CH.sub.3   CH.sub.3                                                                          H   H   S  2                                          1.65                                                                               H  H   H          H  CH.sub.3                                                                           H   S  0                                          1.66                                                                               H  H   H          H  CH.sub.3                                                                           H   S  2                                          1.67                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           H   S  0                                          1.68                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           H   S  2                                          1.69                                                                               H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           H   S  0                                          1.70                                                                               H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           H   S  2                                          1.71                                                                               H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           H   S  0                                          1.72                                                                               H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           H   S  2                                          1.73                                                                               H  H   H          H  Cl  H   S  0                                          1.74                                                                               H  H   H          H  Cl  H   S  2                                          1.75                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  H   S  0                                          1.76                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  H   S  2                                          1.77                                                                               H  H   H          CH.sub.3                                                                          Cl  H   S  0                                          1.78                                                                               H  H   H          CH.sub.3                                                                          Cl  H   S  2                                          1.79                                                                               H  H   CH.sub.3   CH.sub.3                                                                          Cl  H   S  0                                          1.80                                                                               H  H   CH.sub.3   CH.sub.3                                                                          Cl  H   S  2                                          1.81                                                                               H  H   H          H  Cl  Cl  S  0                                          1.82                                                                               H  H   H          H  Cl  Cl  S  2                                          1.83                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  Cl  S  0                                          1.84                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  Cl  S  2                                          1.85                                                                               H  H   H          CH.sub.3                                                                          Cl  Cl  S  0                                          1.86                                                                               H  H   H          CH.sub.3                                                                          Cl  Cl  S  2                                          1.87                                                                               H  H   CH.sub.3   CH.sub.3                                                                          Cl  Cl  S  0                                          1.88                                                                               H  H   CH.sub.3   CH.sub.3                                                                          Cl  Cl  S  2                                          1.89                                                                               H  H   H          H  CH.sub.3                                                                           CH.sub.3                                                                           S  0                                          1.90                                                                               H  H   H          H  CH.sub.3                                                                           CH.sub.3                                                                           S  2                                          1.91                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           CH.sub.3                                                                           S  0                                          1.92                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           CH.sub.3                                                                           S  2                                          1.93                                                                               H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  0                                          1.94                                                                               H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  2                                          1.95                                                                               H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  0                                          1.96                                                                               H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  2                                          1.97                                                                               H  H   H          H  NO.sub.2                                                                           H   S  0                                          1.98                                                                               H  H   H          H  NO.sub.2                                                                           H   S  2                                          1.99                                                                               CH.sub.3                                                                          CH.sub.3                                                                           H          H  NO.sub.2                                                                           H   S  0                                          1.100                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  NO.sub.2                                                                           H   S  2                                          1.101                                                                              H  H   H          CH.sub.3                                                                          NO.sub.2                                                                           H   S  0                                          1.102                                                                              H  H   H          CH.sub.3                                                                          NO.sub.2                                                                           H   S  2                                          1.103                                                                              H  H   CH.sub.3   CH.sub.3                                                                          NO.sub.2                                                                           H   S  0                                          1.104                                                                              H  H   CH.sub.3   CH.sub.3                                                                          NO.sub.2                                                                           H   S  2                                          1.105                                                                              H  H   H          H  OCH.sub.3                                                                          H   S  0                                          1.106                                                                              H  H   H          H  OCH.sub.3                                                                          H   S  2                                          1.107                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  OCH.sub.3                                                                          H   S  0                                          1.108                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  OCH.sub.3                                                                          H   S  2                                          1.109                                                                              H  H   H          CH.sub.3                                                                          OCH.sub.3                                                                          H   S  0                                          1.110                                                                              H  H   H          CH.sub.3                                                                          OCH.sub.3                                                                          H   S  2                                          1.111                                                                              H  H   CH.sub.3   CH.sub.3                                                                          OCH.sub.3                                                                          H   S  0                                          1.112                                                                              H  H   CH.sub.3   CH.sub.3                                                                          OCH.sub.3                                                                          H   S  2                                          1.113                                                                              H  H   H          H  H   H   SO.sub.2                                                                          0                                          1.114                                                                              H  H   H          H  H   H   SO.sub.2                                                                          2                                          1.115                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  H   H   SO.sub.2                                                                          0                                          1.116                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  H   H   SO.sub.2                                                                          2                                          1.117                                                                              H  H   H          CH.sub.3                                                                          H   H   SO.sub.2                                                                          0                                          1.118                                                                              H  H   H          CH.sub.3                                                                          H   H   SO.sub.2                                                                          2                                          1.119                                                                              H  H   CH.sub.3   CH.sub.3                                                                          H   H   SO.sub.2                                                                          0                                          1.120                                                                              H  H   CH.sub.3   CH.sub.3                                                                          H   H   SO.sub.2                                                                          2                                          1.121                                                                              H  H   H          H  CH.sub.3                                                                           H   SO.sub.2                                                                          0                                          1.122                                                                              H  H   H          H  CH.sub.3                                                                           H   SO.sub.2                                                                          2                                          1.123                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           H   SO.sub.2                                                                          0                                          1.124                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           H   SO.sub.2                                                                          2                                          1.125                                                                              H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          0                                          1.126                                                                              H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          2                                          1.127                                                                              H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          0                                          1.128                                                                              H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          2                                          1.129                                                                              H  H   H          H  Cl  H   SO.sub.2                                                                          0                                          1.130                                                                              H  H   H          H  Cl  H   SO.sub.2                                                                          2                                          1.131                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  H   SO.sub.2                                                                          0                                          1.132                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  H   SO.sub.2                                                                          2                                          1.133                                                                              H  H   H          CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          0                                          1.134                                                                              H  H   H          CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          2                                          1.135                                                                              H  H   CH.sub.3   CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          0                                          1.136                                                                              H  H   CH.sub.3   CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          2                                          1.137                                                                              H  H   H          H  Cl  Cl  SO.sub.2                                                                          0                                          1.138                                                                              H  H   H          H  Cl  Cl  SO.sub.2                                                                          2                                          1.139                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  Cl  SO.sub.2                                                                          0                                          1.140                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  Cl  Cl  SO.sub.2                                                                          2                                          1.141                                                                              H  H   H          CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          0                                          1.142                                                                              H  H   H          CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          2                                          1.143                                                                              H  H   CH.sub.3   CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          0                                          1.144                                                                              H  H   CH.sub.3   CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          2                                          1.145                                                                              H  H   H          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                          1.146                                                                              H  H   H          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                          1.147                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                          1.148                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                          1.149                                                                              H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                          1.150                                                                              H  H   H          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                          1.151                                                                              H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                          1.152                                                                              H  H   CH.sub.3   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                          1.153                                                                              H  H   H          H  NO.sub.2                                                                           H   SO.sub.2                                                                          0                                          1.154                                                                              H  H   H          H  NO.sub.2                                                                           H   SO.sub.2                                                                          2                                          1.155                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  NO.sub.2                                                                           H   SO.sub.2                                                                          0                                          1.156                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  NO.sub.2                                                                           H   SO.sub.2                                                                          2                                          1.157                                                                              H  H   H          CH.sub.3                                                                          NO.sub.2                                                                           H   SO.sub.2                                                                          0                                          1.158                                                                              H  H   H          CH.sub.3                                                                          NO.sub.2                                                                           H   SO.sub.2                                                                          2                                          1.159                                                                              H  H   CH.sub.3   CH.sub.3                                                                          NO.sub.                                                                            H   SO.sub.2                                                                          0                                          1.160                                                                              H  H   CH.sub.3   CH.sub.3                                                                          NO.sub.2                                                                           H   SO.sub.2                                                                          2                                          1.161                                                                              H  H   H          H  OCH.sub.3                                                                          H   SO.sub.2                                                                          0                                          1.162                                                                              H  H   H          H  OCH.sub.3                                                                          H   SO.sub.2                                                                          2                                          1.163                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  OCH.sub.3                                                                          H   SO.sub.2                                                                          0                                          1.164                                                                              CH.sub.3                                                                          CH.sub.3                                                                           H          H  OCH.sub.3                                                                          H   SO.sub.2                                                                          2                                          1.165                                                                              H  H   H          CH.sub.3                                                                          OCH.sub.3                                                                          H   SO.sub.2                                                                          0                                          1.166                                                                              H  H   H          CH.sub.3                                                                          OCH.sub.3                                                                          H   SO.sub.2                                                                          2                                          1.167                                                                              H  H   CH.sub.3   CH.sub.3                                                                          OCH.sub.3                                                                          H   SO.sub.2                                                                          0                                          1.168                                                                              H  H   CH.sub.3   CH.sub.3                                                                          OCH.sub.3                                                                          H   SO.sub.2                                                                          2                                          1.169                                                                              H  H   2-Ethylthiopropyl                                                                         H  H   H   O  0                                          1.170                                                                              H  H   2-Ethylthiopropyl                                                                         H  H   H   O  2                                          1.171                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           H   O  0                                          1.172                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           H   O  0                                          1.173                                                                              H  H   2-Etbylthiopropyl                                                                         H  Cl  H   O  0                                          1.174                                                                              H  H   2-Ethylthiopropyl                                                                         H  Cl  H   O  2                                          1.175                                                                              H  H   2-Ethylthiopropyl                                                                         H  Cl  Cl  O  0                                          1.176                                                                              H  H   2-Ethylthiopropyl                                                                         H  Cl  Cl  O  2                                          1.177                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           CH.sub.3                                                                           O  0                                          1.178                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           CH.sub.3                                                                           O  2                                          1.179                                                                              H  H   2-Ethylthiopropyl                                                                         H  NO.sub.2                                                                           H   O  0                                          1.180                                                                              H  H   2-Ethylthiopropyl                                                                         H  NO.sub.2                                                                           H   O  2                                          1.181                                                                              H  H   2-Ethylthiopropyl                                                                         H  OCH.sub.3                                                                          H   O  0                                          1.182                                                                              H  H   2-Ethylthiopropyl                                                                         H  OCH.sub.3                                                                          H   O  2                                          1.183                                                                              H  H   2-Ethylthiopropyl                                                                         H  H   H   S  0                                          1.184                                                                              H  H   2-Ethylthiopropyl                                                                         H  H   H   S  2                                          1.185                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           H   S  0                                          1.186                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           H   S  2                                          1.187                                                                              H  H   2-Ethylthiopropyl                                                                         H  Cl  H   S  0                                          1.188                                                                              H  H   2-Ethylthiopropyl                                                                         H  Cl  H   S  2                                          1.189                                                                              H  H   2-Ethylthiopropyl                                                                         H  Cl  Cl  S  0                                          1.190                                                                              H  H   2-Ethylthiopropyl                                                                         H  Cl  Cl  S  2                                          1.191                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           CH.sub.3                                                                           S  0                                          1.192                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           CH.sub.3                                                                           S  2                                          1.193                                                                              H  H   2-Ethylthiopropyl                                                                         H  H   H   SO.sub.2                                                                          0                                          1.194                                                                              H  H   2-Ethylthiopropyl                                                                         H  H   H   SO.sub.2                                                                          2                                          1.195                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           H   SO.sub.2                                                                          0                                          1.196                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           H   SO.sub.2                                                                          2                                          1.197                                                                              H  H   2-Ethylthiopropyl                                                                         H  Cl  H   SO.sub.2                                                                          0                                          1.198                                                                              H  H   2-Ethylthiopropyl                                                                         H  Cl  H   SO.sub.2                                                                          2                                          1.199                                                                              H  H   2-Ethylthiopropyl                                                                         H  Cl  Cl  SO.sub.2                                                                          0                                          1.200                                                                              H  H   2-Ethylthiopropyl                                                                         H  Cl  Cl  SO.sub.2                                                                          2                                          1.201                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                          1.202                                                                              H  H   2-Ethylthiopropyl                                                                         H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                          1.203                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  H   H   O  0                                          1.204                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  H   H   O  2                                          1.205                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           H   O  0                                          1.206                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           H   O  0                                          1.207                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  H   O  0                                          1.208                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  H   O  2                                          1.209                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  Cl  O  0                                          1.210                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  Cl  O  2                                          1.211                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           CH.sub.3                                                                           O  0                                          1.212                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           CH.sub.3                                                                           O  2                                          1.213                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  NO.sub.2                                                                           H   O  0                                          1.214                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  NO.sub.2                                                                           H   O  2                                          1.215                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  OCH.sub.3                                                                          H   O  0                                          1.216                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  OCH.sub.3                                                                          H   O  2                                          1.217                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  H   H   S  0                                          1.218                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  H   H   S  2                                          1.219                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           H   S  0                                          1.220                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           H   S  2                                          1.221                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  H   S  0                                          1.222                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  H   S  2                                          1.223                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  Cl  S  0                                          1.224                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  Cl  S  2                                          1.225                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           CH.sub.3                                                                           S  0                                          1.226                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           CH.sub.3                                                                           S  2                                          1.227                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  H   H   SO.sub.2                                                                          0                                          1.228                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  H   H   SO.sub.2                                                                          2                                          1.229                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           H   SO.sub.2                                                                          0                                          1.230                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           H   SO.sub.2                                                                          2                                          1.231                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  H   SO.sub.2                                                                          0                                          1.232                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  H   SO.sub.2                                                                          2                                          1.233                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  Cl  SO.sub.2                                                                          0                                          1.234                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  Cl  Cl  SO.sub.2                                                                          2                                          1.235                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                          1.236                                                                              H  H   Tetrahydropyran-3-yl                                                                      H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                          1.237                                                                              H  H   Tetrahydropyran-4-yl                                                                      H  CH.sub.3                                                                           H   0  2                                          1.238                                                                              H  H   Tetrahydropyran-4-yl                                                                      H  Cl  H   O  2                                          1.239                                                                              H  H   Tetrahydropyran-4-yl                                                                      H  Cl  Cl  O  2                                          1.240                                                                              H  H   Tetrahydropyran-4-yl                                                                      H  CH.sub.3                                                                           CH.sub.3                                                                           O  2                                          1.241                                                                              H  H   Tetrahydropyran-4-yl                                                                      H  CH.sub.3                                                                           H   S  2                                          1.242                                                                              H  H   Tetrahydropyran-4-yl                                                                      H  Cl  H   S  2                                          1.243                                                                              H  H   Tetrahydropyran-4-yl                                                                      H  CH.sub.3                                                                           H   SO.sub.2                                                                          2                                          1.244                                                                              H  H   Tetrahydropyran-4-yl                                                                      H  Cl  H   SO.sub.2                                                                          2                                          1.245                                                                              R  H   1-Methylthiocyclo-                                                                        H  CH.sub.3                                                                           H   O  2                                                     propyl                                                              1.246                                                                              H  H   1-Methylthiocyclo-                                                                        H  Cl  H   O  2                                                     propyl                                                              1.247                                                                              H  H   1-Methylthiocyclo-                                                                        H  Cl  Cl  O  2                                                     propyl                                                              1.248                                                                              H  H   1-Methylthiocyclo-                                                                        H  CH.sub.3                                                                           CH.sub.3                                                                           O  2                                                     propyl                                                              1.249                                                                              H  H   1-Methylthiocyclo-                                                                        H  CH.sub.3                                                                           H   S  2                                                     propyl                                                              1.250                                                                              H  H   1-Methylthiocyclo-                                                                        H  Cl  H   S  2                                                     propyl                                                              1.251                                                                              H  H   1-Methylthiocyclo-                                                                        H  CH.sub.3                                                                           H   SO.sub.2                                                                          2                                                     propyl                                                              1.252                                                                              H  H   1-Methylthiocyclo-                                                                        H  Cl  H   SO.sub.2                                                                          2                                                     propyl                                                              1.253                                                                              H  H   (Dimethoxy)methyl                                                                         H  CH.sub.3                                                                           H   O  2                                          1.254                                                                              H  H   (Dimethoxy)methyl                                                                         H  Cl  H   O  2                                          1.255                                                                              H  H   (Dimethoxy)methyl                                                                         H  Cl  Cl  O  2                                          1.256                                                                              H  H   (Dimethoxy)methyl                                                                         H  CH.sub.3                                                                           CH.sub.3                                                                           O  2                                          1.257                                                                              H  H   (Dimethoxy)methyl                                                                         H  CH.sub.3                                                                           H   S  2                                          1.258                                                                              H  H   (Dimethoxy)methyl                                                                         H  Cl  H   S  2                                          1.259                                                                              H  H   (Dimethoxy)methyl                                                                         H  CH.sub.3                                                                           H   SO.sub.2                                                                          2                                          1.260                                                                              H  H   (Dimethoxy)methyl                                                                         H  Cl  H   SO.sub.2                                                                          2                                          __________________________________________________________________________

                  TABLE 2                                                          ______________________________________                                          ##STR15##                                                                     No.   R.sup.5                                                                               R.sup.6 R.sup.7                                                                             R.sup.8                                                                              L    M     X    n                              ______________________________________                                         2.1   H      H       H    H     CH.sub.3                                                                            H     O    0                              2.2   H      H       H    H     CH.sub.3                                                                            H     O    2                              2.3   CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     O    0                              2.4   CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     O    2                              2.5   H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     O    0                              2.6   H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     O    2                              2.7   H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     O    0                              2.8   H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     O    2                              2.9   H      H       H    H     Cl   H     O    0                              2.10  H      H       H    H     Cl   H     O    2                              2.11  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     O    0                              2.12  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     O    2                              2.13  H      H       H    CH.sub.3                                                                             Cl   H     O    0                              2.14  H      H       H    CH.sub.3                                                                             Cl   H     O    2                              2.15  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     O    0                              2.16  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     O    2                              2.17  H      H       H    H     Cl   Cl    O    0                              2.18  H      H       H    H     Cl   Cl    O    2                              2.19  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    O    0                              2.20  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    O    2                              2.21  H      H       H    CH.sub.3                                                                             Cl   Cl    O    0                              2.22  H      H       H    CH.sub.3                                                                             Cl   Cl    O    2                              2.23  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    O    0                              2.24  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    O    2                              2.25  H      H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             O    0                              2.26  H      H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             O    2                              2.27  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             O    0                              2.28  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             O    2                              2.29  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             O    0                              2.30  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             O    2                              2.31  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             O    0                              2.32  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             O    2                              2.33  H      H       H    H     CH.sub.3                                                                            H     S    0                              2.34  H      H       H    H     CH.sub.3                                                                            H     S    2                              2.35  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     S    0                              2.36  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     S    2                              2.37  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     S    0                              2.38  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     S    2                              2.39  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     S    0                              2.40  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     S    2                              2.41  H      H       H    H     Cl   H     S    0                              2.42  H      H       H    H     Cl   H     S    2                              2.43  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     S    0                              2.44  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     S    2                              2.45  H      H       H    CH.sub.3                                                                             Cl   H     S    0                              2.46  H      H       H    CH.sub.3                                                                             Cl   H     S    2                              2.47  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     S    0                              2.48  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     S    2                              2.49  H      H       H    H     Cl   Cl    S    0                              2.50  H      H       H    H     Cl   Cl    S    2                              2.51  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    S    0                              2.52  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    S    2                              2.53  H      H       H    CH.sub.3                                                                             Cl   Cl    S    0                              2.54  H      H       H    CH.sub.3                                                                             Cl   Cl    S    2                              2.55  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    S    0                              2.56  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    S    2                              2.57  H      H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             S    0                              2.58  H      H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             S    2                              2.59  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             S    0                              2.60  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             S    2                              2.61  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             S    0                              2.62  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             S    2                              2.63  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             S    0                              2.64  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             S    2                              2.65  H      H       H    H     CH.sub.3                                                                            H     SO.sub.2                                                                            0                              2.66  H      H       H    H     CH.sub.3                                                                            H     SO.sub.2                                                                            2                              2.67  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     SO.sub.2                                                                            0                              2.68  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     SO.sub.2                                                                            2                              2.69  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     SO.sub.2                                                                            0                              2.70  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     SO.sub.2                                                                            2                              2.71  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     SO.sub.2                                                                            0                              2.72  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     SO.sub.2                                                                            2                              2.73  H      H       H    H     Cl   H     SO.sub.2                                                                            0                              2.74  H      H       H    H     Cl   H     SO.sub.2                                                                            2                              2.75  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     SO.sub.2                                                                            0                              2.76  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     SO.sub.2                                                                            2                              2.77  H      H       H    CH.sub.3                                                                             Cl   H     SO.sub.2                                                                            0                              2.78  H      H       H    CH.sub.3                                                                             Cl   H     SO.sub.2                                                                            2                              2.79  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     SO.sub.2                                                                            0                              2.80  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     SO.sub.2                                                                            2                              2.81  H      H       H    H     Cl   Cl    SO.sub.2                                                                            0                              2.82  H      H       H    H     Cl   Cl    SO.sub.2                                                                            2                              2.83  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    SO.sub.2                                                                            0                              2.84  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    SO.sub.2                                                                            2                              2.85  H      H       H    CH.sub.3                                                                             Cl   Cl    SO.sub.2                                                                            0                              2.86  H      H       H    CH.sub.3                                                                             Cl   Cl    SO.sub.2                                                                            2                              2.87  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    SO.sub.2                                                                            0                              2.88  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    SO.sub.2                                                                            2                              2.89  H      H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            0                              2.90  H      H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            2                              2.91  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            0                              2.92  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            2                              2.93  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            0                              2.94  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            2                              2.95  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            0                              2.96  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            2                              ______________________________________                                    

                  TABLE 3                                                          ______________________________________                                          ##STR16##                                                                     No.  R.sup.5 R.sup.6                                                                               R.sup.7                                                                              R.sup.8                                                                             M      L    X     n                             ______________________________________                                         7.1  H       H      H     H    H      H    O     0                             7.2  H       H      H     H    H      H    O     2                             7.3  CH.sub.3                                                                               CH.sub.3                                                                              H     H    H      H    O     0                             7.4  CH.sub.3                                                                               CH.sub.3                                                                              H     H    H      H    O     2                             7.5  H       H      H     CH.sub.3                                                                            H      H    O     0                             7.6  H       H      H     CH.sub.3                                                                            H      H    O     2                             7.7  H       H      CH.sub.3                                                                             CH.sub.3                                                                            H      H    O     0                             7.8  H       H      CH.sub.3                                                                             CH.sub.3                                                                            H      H    O     2                             7.9  H       H      H     H    CH.sub.3                                                                              H    O     0                             7.10 H       H      H     H    CH.sub.3                                                                              H    O     2                             7.11 CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              H    O     0                             7.12 CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              H    O     2                             7.13 H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              H    O     0                             7.14 H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              H    O     2                             7.15 H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              H    O     0                             7.16 H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              H    O     2                             7.17 H       H      H     H    Cl     H    O     0                             7.18 H       H      H     H    Cl     H    O     2                             7.19 CH.sub.3                                                                               CH.sub.3                                                                              H     H    Cl     H    O     0                             7.20 CH.sub.3                                                                               CH.sub.3                                                                              H     H    Cl     H    O     2                             7.21 H       H      H     CH.sub.3                                                                            Cl     H    O     0                             7.22 H       H      H     CH.sub.3                                                                            Cl     H    O     2                             7.23 H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     H    O     0                             7.24 H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     H    O     2                             7.25 H       H      H     H    Cl     Cl   O     0                             7.26 H       H      H     H    Cl     Cl   O     2                             7.27 CH.sub.3                                                                               CH.sub.3                                                                              H     H    Cl     Cl   O     0                             7.28 CH.sub.3                                                                               CH.sub.3                                                                              H     R    Cl     Cl   O     2                             7.29 H       H      H     CH.sub.3                                                                            Cl     Cl   O     0                             7.30 H       H      H     CH.sub.3                                                                            Cl     Cl   O     2                             7.31 H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     Cl   O     0                             7.32 H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     Cl   O     2                             7.33 H       H      H     H    CH.sub.3                                                                              CH.sub.3                                                                            O     0                             7.34 H       H      H     H    CH.sub.3                                                                              CH.sub.3                                                                            O     2                             7.35 CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              CH.sub.3                                                                            O     0                             7.36 CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              CH.sub.3                                                                            O     2                             7.37 H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            O     0                             7.38 H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            O     2                             7.39 H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            O     0                             7.40 H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            O     2                             7.41 H       H      H     H    NO.sub.2                                                                              H    O     0                             7.42 H       H      H     H    NO.sub.2                                                                              H    O     2                             7.43 CH.sub.3                                                                               CH.sub.3                                                                              H     H    NO.sub.2                                                                              H    O     0                             7.44 CH.sub.3                                                                               CH.sub.3                                                                              H     H    NO.sub.2                                                                              H    O     2                             7.45 H       H      H     CH.sub.3                                                                            NO.sub.2                                                                              H    O     0                             7.46 H       H      H     CH.sub.3                                                                            NO.sub.2                                                                              H    O     2                             7.47 H       H      CH.sub.3                                                                             CH.sub.3                                                                            NO.sub.2                                                                              H    O     0                             7.48 H       H      CH.sub.3                                                                             CH.sub.3                                                                            NO.sub.2                                                                              H    O     2                             7.49 H       H      H     H    OCH.sub.3                                                                             H    O     0                             7.50 H       H      H     H    OCH.sub.3                                                                             H    O     2                             7.51 CH.sub.3                                                                               CH.sub.3                                                                              H     H    OCH.sub.3                                                                             H    O     0                             7.52 CH.sub.3                                                                               CH.sub.3                                                                              H     H    OCH.sub.3                                                                             H    O     2                             7.53 H       H      H     CH.sub.3                                                                            OCH.sub.3                                                                             H    O     0                             7.54 H       H      H     CH.sub.3                                                                            OCH.sub.3                                                                             H    O     2                             7.55 H       H      CH.sub.3                                                                             CH.sub.3                                                                            OCH.sub.3                                                                             H    O     0                             7.56 H       H      CH.sub.3                                                                             CH.sub.3                                                                            OCH.sub.3                                                                             H    O     2                             7.57 H       H      H     H    H      H    S     0                             7.58 H       H      H     H    H      H    S     2                             7.59 CH.sub.3                                                                               CH.sub.3                                                                              H     H    H      H    S     0                             7.60 CH.sub.3                                                                               CH.sub.3                                                                              H     H    H      H    S     2                             7.61 H       H      H     CH.sub.3                                                                            H      H    S     0                             7.62 H       H      H     CH.sub.3                                                                            H      H    S     2                             7.63 H       H      CH.sub.3                                                                             CH.sub.3                                                                            H      H    S     0                             7.64 H       H      CH.sub.3                                                                             CH.sub.3                                                                            H      H    S     2                             7.65 H       H      H     H    CH.sub.3                                                                              H    S     0                             7.66 H       H      H     H    CH.sub.3                                                                              H    S     2                             7.67 CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              H    S     0                             7.68 CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              H    S     2                             7.69 H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              H    S     0                             7.70 H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              H    S     2                             7.71 H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              H    S     0                             7.72 H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              H    S     2                             7.73 H       H      H     H    Cl     H    S     0                             7.74 H       H      H     H    Cl     H    S     2                             7.75 CH.sub.3                                                                               CH.sub.3                                                                              H     H    Cl     H    S     0                             7.76 CH.sub.3                                                                               CH.sub.3                                                                              H     H    Cl     H    S     2                             7.77 H       H      H     CH.sub.3                                                                            Cl     H    S     0                             7.78 H       H      H     CH.sub.3                                                                            Cl     H    S     2                             7.79 H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     H    S     0                             7.80 H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     H    S     2                             7.81 H       H      H     H    Cl     Cl   S     0                             7.82 H       H      H     H    Cl     Cl   S     2                             7.83 CH.sub.3                                                                               CH.sub.3                                                                              H     H    Cl     Cl   S     0                             7.84 CH.sub.3                                                                               CH.sub.3                                                                              H     H    Cl     Cl   S     2                             7.85 H       H      H     CH.sub.3                                                                            Cl     Cl   S     0                             7.86 H       H      H     CH.sub.3                                                                            Cl     Cl   S     2                             7.87 H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     Cl   S     0                             7.88 H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     Cl   S     2                             7.89 H       H      H     H    CH.sub.3                                                                              CH.sub.3                                                                            S     0                             7.90 H       H      H     H    CH.sub.3                                                                              CH.sub.3                                                                            S     2                             7.91 CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              CH.sub.3                                                                            S     0                             7.92 CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              CH.sub.3                                                                            S     2                             7.93 H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            S     0                             7.94 H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            S     2                             7.95 H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            S     0                             7.96 H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            S     2                             7.97 H       H      H     H    NO.sub.2                                                                              H    S     0                             7.98 H       H      H     H    NO.sub.2                                                                              H    S     2                             7.99 CH.sub.3                                                                               CH.sub.3                                                                              H     H    NO.sub.2                                                                              H    S     0                             7.100                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    NO.sub.2                                                                              H    S     2                             7.101                                                                               H       H      H     CH.sub.3                                                                            NO.sub.2                                                                              H    S     0                             7.102                                                                               H       H      H     CH.sub.3                                                                            NO.sub.2                                                                              H    S     2                             7.103                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            NO.sub.2                                                                              H    S     0                             7.104                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            NO.sub.2                                                                              H    S     2                             7.105                                                                               H       H      H     H    OCH.sub.3                                                                             H    S     0                             7.106                                                                               H       H      H     H    OCH.sub.3                                                                             H    S     2                             7.107                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    OCH.sub.3                                                                             H    S     0                             7.108                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    OCH.sub.3                                                                             H    S     2                             7.109                                                                               H       H      H     CH.sub.3                                                                            OCH.sub.3                                                                             H    S     0                             7.110                                                                               H       H      H     CH.sub.3                                                                            OCH.sub.3                                                                             H    S     2                             7.111                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            OCH.sub.3                                                                             H    S     0                             7.112                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            OCH.sub.3                                                                             H    S     2                             7.113                                                                               H       H      H     H    H      H    SO.sub.2                                                                             0                             7.114                                                                               H       H      H     H    H      H    SO.sub.2                                                                             2                             7.115                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    H      H    SO.sub.2                                                                             0                             7.116                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    H      H    SO.sub.2                                                                             2                             7.117                                                                               H       H      H     CH.sub.3                                                                            H      H    SO.sub.2                                                                             0                             7.118                                                                               H       H      H     CH.sub.3                                                                            H      H    SO.sub.2                                                                             2                             7.119                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            H      H    SO.sub.2                                                                             0                             7.120                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            H      H    SO.sub.2                                                                             2                             7.121                                                                               H       H      H     H    CH.sub.3                                                                              H    SO.sub.2                                                                             0                             7.122                                                                               H       H      H     H    CH.sub.3                                                                              H    SO.sub.2                                                                             2                             7.123                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              H    SO.sub.2                                                                             0                             7.124                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              H    SO.sub.2                                                                             2                             7.125                                                                               H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              H    SO.sub.2                                                                             0                             7.126                                                                               H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              H    SO.sub.2                                                                             2                             7.127                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              H    SO.sub.2                                                                             0                             7.128                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              H    SO.sub.2                                                                             2                             7.129                                                                               H       H      H     H    Cl     H    SO.sub.2                                                                             0                             7.130                                                                               H       H      H     H    Cl     H    SO.sub.2                                                                             2                             7.131                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    Cl     H    SO.sub.2                                                                             0                             7.132                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    Cl     H    SO.sub.2                                                                             2                             7.133                                                                               H       H      H     CH.sub.3                                                                            Cl     H    SO.sub.2                                                                             0                             7.134                                                                               H       H      H     CH.sub.3                                                                            Cl     H    SO.sub.2                                                                             2                             7.135                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     H    SO.sub.2                                                                             0                             7.136                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     H    SO.sub.2                                                                             2                             7.137                                                                               H       H      H     H    Cl     Cl   SO.sub.2                                                                             0                             7.138                                                                               H       H      H     H    Cl     Cl   SO.sub.2                                                                             2                             7.139                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    Cl     Cl   SO.sub.2                                                                             0                             7.140                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    Cl     Cl   SO.sub.2                                                                             2                             7.141                                                                               H       H      H     CH.sub.3                                                                            Cl     Cl   SO.sub.2                                                                             0                             7.142                                                                               H       H      H     CH.sub.3                                                                            Cl     Cl   SO.sub.2                                                                             2                             7.143                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     Cl   SO.sub.2                                                                             0                             7.144                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            Cl     Cl   SO.sub.2                                                                             2                             7.145                                                                               H       H      H     H    CH.sub.3                                                                              CH.sub.3                                                                            SO.sub.2                                                                             0                             7.146                                                                               H       H      H     H    CH.sub.3                                                                              CH.sub.3                                                                            SO.sub.2                                                                             2                             7.147                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              CH.sub.3                                                                            SO.sub.2                                                                             0                             7.148                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    CH.sub.3                                                                              CH.sub.3                                                                            SO.sub.2                                                                             2                             7.149                                                                               H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            SO.sub.2                                                                             0                             7.150                                                                               H       H      H     CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            SO.sub.2                                                                             2                             7.151                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            SO.sub.2                                                                             0                             7.152                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                              CH.sub.3                                                                            SO.sub.2                                                                             2                             7.153                                                                               H       H      H     H    NO.sub.2                                                                              H    SO.sub.2                                                                             0                             7.154                                                                               H       H      H     H    NO.sub.2                                                                              H    SO.sub.2                                                                             2                             7.155                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    NO.sub.2                                                                              H    SO.sub.2                                                                             0                             7.156                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    NO.sub.2                                                                              H    SO.sub.2                                                                             2                             7.157                                                                               H       H      H     CH.sub.3                                                                            NO.sub.2                                                                              H    SO.sub.2                                                                             0                             7.158                                                                               H       H      H     CH.sub.3                                                                            NO.sub.2                                                                              H    SO.sub.2                                                                             2                             7.159                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            NO.sub.2                                                                              H    SO.sub.2                                                                             0                             7.160                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            NO.sub.2                                                                              H    SO.sub.2                                                                             2                             7.161                                                                               H       H      H     H    OCH.sub.3                                                                             H    SO.sub.2                                                                             0                             7.162                                                                               H       H      H     H    OCH.sub.3                                                                             H    SO.sub.2                                                                             2                             7.163                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    OCH.sub.3                                                                             H    SO.sub.2                                                                             0                             7.164                                                                               CH.sub.3                                                                               CH.sub.3                                                                              H     H    OCH.sub.3                                                                             H    SO.sub.2                                                                             2                             7.165                                                                               H       H      H     CH.sub.3                                                                            OCH.sub.3                                                                             H    SO.sub.2                                                                             0                             7.166                                                                               H       H      H     CH.sub.3                                                                            OCH.sub.3                                                                             H    SO.sub.2                                                                             2                             7.167                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            OCH.sub.3                                                                             H    SO.sub.2                                                                             0                             7.168                                                                               H       H      CH.sub.3                                                                             CH.sub.3                                                                            OCH.sub.3                                                                             H    SO.sub.2                                                                             2                             ______________________________________                                    

                  TABLE 4                                                          ______________________________________                                          ##STR17##                                                                     No.   R.sup.5                                                                               R.sup.6 R.sup.7                                                                             R.sup.8                                                                              L    M     X    n                              ______________________________________                                         4.1   H      H       H    H     CH.sub.3                                                                            H     O    0                              4.2   H      H       H    H     CH.sub.3                                                                            H     O    2                              4.3   CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     O    0                              4.4   CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     O    2                              4.5   H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     O    0                              4.6   H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     O    2                              4.7   H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     O    0                              4.8   H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     O    2                              4.9   H      H       H    H     Cl   H     O    0                              4.10  H      H       H    H     Cl   H     O    2                              4.11  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     O    0                              4.12  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     O    2                              4.13  H      H       H    CH.sub.3                                                                             Cl   H     O    0                              4.14  H      H       H    CH.sub.3                                                                             Cl   H     O    2                              4.15  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     O    0                              4.16  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     O    2                              4.17  H      H       H    H     Cl   Cl    O    0                              4.18  H      H       H    H     Cl   Cl    O    2                              4.19  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    O    0                              4.20  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    O    2                              4.21  H      H       H    CH.sub.3                                                                             Cl   Cl    O    0                              4.22  H      H       H    CH.sub.3                                                                             Cl   Cl    O    2                              4.23  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    O    0                              4.24  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    O    2                              4.25  H      H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             O    0                              4.26  H      H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             O    2                              4.27  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             O    0                              4.28  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             O    2                              4.29  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             O    0                              4.30  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             O    2                              4.31  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             O    0                              4.32  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             O    2                              4.33  H      H       H    H     CH.sub.3                                                                            H     S    0                              4.34  H      H       H    H     CH.sub.3                                                                            H     S    2                              4.35  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     S    0                              4.36  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     S    2                              4.37  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     S    0                              4.38  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     S    2                              4.39  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     S    0                              4.40  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     S    2                              4.41  H      H       H    H     Cl   H     S    0                              4.42  H      H       H    H     Cl   H     S    2                              4.43  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     S    0                              4.44  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     S    2                              4.45  H      H       H    CH.sub.3                                                                             Cl   H     S    0                              4.46  H      H       H    CH.sub.3                                                                             Cl   H     S    2                              4.47  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     S    0                              4.48  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     S    2                              4.49  H      H       H    H     Cl   Cl    S    0                              4.50  H      H       H    H     Cl   Cl    S    2                              4.51  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    S    0                              4.52  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    S    2                              4.53  H      H       H    CH.sub.3                                                                             Cl   Cl    S    0                              4.54  H      H       H    CH.sub.3                                                                             Cl   Cl    S    2                              4.55  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    S    0                              4.56  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    S    2                              4.57  H      H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             S    0                              4.58  14     H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             S    2                              4.59  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             S    0                              4.60  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             S    2                              4.61  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             S    0                              4.62  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             S    2                              4.63  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             S    0                              4.64  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             S    2                              4.65  H      H       H    H     CH.sub.3                                                                            H     SO.sub.2                                                                            0                              4.66  H      H       H    H     CH.sub.3                                                                            H     SO.sub.2                                                                            2                              4.67  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     SO.sub.2                                                                            0                              4.68  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            H     SO.sub.2                                                                            2                              4.69  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     SO.sub.2                                                                            0                              4.70  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            H     SO.sub.2                                                                            2                              4.71  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     SO.sub.2                                                                            0                              4.72  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            H     SO.sub.2                                                                            2                              4.73  H      H       H    H     Cl   H     SO.sub.2                                                                            0                              4.74  H      H       H    H     Cl   H     SO.sub.2                                                                            2                              4.75  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     SO.sub.2                                                                            0                              4.76  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   H     SO.sub.2                                                                            2                              4.77  H      H       H    CH.sub.3                                                                             Cl   H     SO.sub.2                                                                            0                              4.78  H      H       H    CH.sub.3                                                                             Cl   H     SO.sub.2                                                                            2                              4.79  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     SO.sub.2                                                                            0                              4.80  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   H     SO.sub.2                                                                            2                              4.81  H      H       H    H     Cl   Cl    SO.sub.2                                                                            0                              4.82  H      H       H    H     Cl   Cl    SO.sub.2                                                                            2                              4.83  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    SO.sub.2                                                                            0                              4.84  CH.sub.3                                                                              CH.sub.3                                                                               H    H     Cl   Cl    SO.sub.2                                                                            2                              4.85  H      H       H    CH.sub.3                                                                             Cl   Cl    SO.sub.2                                                                            0                              4.86  H      H       H    CH.sub.3                                                                             Cl   Cl    SO.sub.2                                                                            2                              4.87  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    SO.sub.2                                                                            0                              4.88  H      H       CH.sub.3                                                                            CH.sub.3                                                                             Cl   Cl    SO.sub.2                                                                            2                              4.89  H      H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            0                              4.90  H      H       H    H     CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            2                              4.91  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            0                              4.92  CH.sub.3                                                                              CH.sub.3                                                                               H    H     CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            2                              4.93  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            0                              4.94  H      H       H    CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            2                              4.95  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            0                              4.96  H      H       CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH.sub.3                                                                             SO.sub.2                                                                            2                              ______________________________________                                    

                                      TABLE 5                                      __________________________________________________________________________      ##STR18##                                                                     No.                                                                               R.sup.5                                                                           R.sup.6                                                                           R.sup.7                                                                           R.sup.8                                                                           R.sup.1                                                                          R.sup.2                                                                           R.sup.3                                                                           R.sup.4                                                                           M   L  X  n                                          __________________________________________________________________________     5.1                                                                               H  H  H  H  H H  CH.sub.3                                                                          H  H   H  O  0                                          5.2                                                                               H  H  H  H  H H  CH.sub.3                                                                          H  H   H  O  2                                          5.3                                                                               CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  H   H  O  0                                          5.4                                                                               CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  H   H  O  2                                          5.5                                                                               H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  O  0                                          5.6                                                                               H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  O  2                                          5.7                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  O  0                                          5.8                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  O  2                                          5.9                                                                               H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  O  0                                          5.10                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  O  2                                          5.11                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  O  0                                          5.12                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  O  2                                          5.13                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  O  0                                          5.14                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  O  2                                          5.15                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  O  0                                          5.16                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  O  2                                          5.17                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  Cl  H  O  0                                          5.18                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  Cl  H  O  2                                          5.19                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  H  O  0                                          5.20                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  H  O  2                                          5.21                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  O  0                                          5.22                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  O  2                                          5.23                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  O  0                                          5.24                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  O  2                                          5.25                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  Cl  Cl O  0                                          5.26                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  Cl  Cl O  2                                          5.27                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  Cl O  0                                          5.28                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  Cl O  2                                          5.29                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl O  0                                          5.30                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl O  2                                          5.31                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl O  0                                          5.32                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl O  2                                          5.33                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.34                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.35                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.36                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.37                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.38                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.39                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.40                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.41                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  O  0                                          5.42                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  O  2                                          5.43                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  O  0                                          5.44                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  O  2                                          5.45                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  O  0                                          5.46                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  O  2                                          5.47                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  O  0                                          5.48                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  O  2                                          5.49                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  H   H  S  0                                          5.50                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  H   H  S  2                                          5.51                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  H   H  S  0                                          5.52                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  H   H  S  2                                          5.53                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  S  0                                          5.54                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  S  2                                          5.55                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  S  0                                          5.56                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  S  2                                          5.57                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  S  0                                          5.58                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  S  2                                          5.59                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  S  0                                          5.60                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  S  2                                          5.61                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  S  0                                          5.62                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  S  2                                          5.63                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  S  0                                          5.64                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  S  2                                          5.65                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  Cl  H  S  0                                          5.66                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  Cl  H  S  2                                          5.67                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  H  S  0                                          5.68                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  H  S  2                                          5.69                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  S  0                                          5.70                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  S  2                                          5.71                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  S  0                                          5.72                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  S  2                                          5.73                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  Cl  Cl S  0                                          5.74                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  Cl  Cl S  2                                          5.75                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  Cl S  0                                          5.76                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  Cl S  2                                          5.77                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl S  0                                          5.78                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl S  2                                          5.79                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl S  0                                          5.80                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl S  2                                          5.81                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.82                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.83                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.84                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.85                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.86                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.87                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.88                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.89                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  S  0                                          5.90                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  S  2                                          5.91                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  S  0                                          5.92                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  S  2                                          5.93                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  S  0                                          5.94                                                                              H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  S  2                                          5.95                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  S  0                                          5.96                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  OCH.sub.3                                                                          H  S  2                                          5.97                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  H   H  SO.sub.2                                                                          0                                          5.98                                                                              H  H  H  H  H H  CH.sub.3                                                                          H  H   H  SO.sub.2                                                                          2                                          5.99                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  H   H  SO.sub.2                                                                          0                                          5.100                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  H   H  SO.sub.2                                                                          2                                          5.101                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  SO.sub.2                                                                          0                                          5.102                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  SO.sub.2                                                                          2                                          5.103                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  SO.sub.2                                                                          0                                          5.104                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  H   H  SO.sub.2                                                                          2                                          5.105                                                                             H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.106                                                                             H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.107                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.108                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.109                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.110                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.111                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.112                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.113                                                                             H  H  H  H  H H  CH.sub.3                                                                          H  Cl  H  SO.sub.2                                                                          0                                          5.114                                                                             H  H  H  H  H H  CH.sub.3                                                                          H  Cl  H  SO.sub.2                                                                          2                                          5.115                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  H  SO.sub.2                                                                          0                                          5.116                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  H  SO.sub.2                                                                          2                                          5.117                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  SO.sub.2                                                                          0                                          5.118                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  SO.sub.2                                                                          2                                          5.119                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  SO.sub.2                                                                          0                                          5.120                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  H  SO.sub.2                                                                          2                                          5.121                                                                             H  H  H  H  H H  CH.sub.3                                                                          H  Cl  Cl SO.sub.2                                                                          0                                          5.122                                                                             H  H  H  H  H H  CH.sub.3                                                                          H  Cl  Cl SO.sub.2                                                                          2                                          5.123                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  Cl SO.sub.2                                                                          0                                          5.124                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  Cl  Cl SO.sub.2                                                                          2                                          5.125                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl SO.sub.2                                                                          0                                          5.126                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl SO.sub.2                                                                          2                                          5.127                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl SO.sub.2                                                                          0                                          5.128                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  Cl  Cl SO.sub.2                                                                          2                                          5.129                                                                             H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.130                                                                             H  H  H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          5.131                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.132                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          5.133                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.134                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          5.135                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.136                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          5.137                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  O  0                                          5.138                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  O  2                                          5.139                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  O  0                                          5.140                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  O  2                                          5.141                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  O  0                                          5.142                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  O  2                                          5.143                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  O  0                                          5.144                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  O  2                                          5.145                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  O  0                                          5.146                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  O  2                                          5.147                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  O  0                                          5.148                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  O  2                                          5.149                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  O  0                                          5.150                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  O  2                                          5.151                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  O  0                                          5.152                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  O  2                                          5.153                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  O  0                                          5.154                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  O  2                                          5.155                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  O  0                                          5.156                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  O  2                                          5.157                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  O  0                                          5.158                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  O  2                                          5.159                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  O  0                                          5.160                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  O  2                                          5.161                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl O  0                                          5.162                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl O  2                                          5.163                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl O  0                                          5.164                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl O  2                                          5.165                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl O  0                                          5.166                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl O  2                                          5.167                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl O  0                                          5.168                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl O  2                                          5.169                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.170                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.171                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.172                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.173                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.174                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.175                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.176                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.177                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  O  0                                          5.178                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  O  2                                          5.179                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  O  0                                          5.180                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  O  2                                          5.181                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  O  0                                          5.182                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  O  2                                          5.183                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  O  0                                          5.184                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  O  2                                          5.185                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  S  0                                          5.186                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  S  2                                          5.187                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  S  0                                          5.188                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  S  2                                          5.189                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  S  0                                          5.190                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  S  2                                          5.191                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  S  0                                          5.192                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  S  2                                          5.193                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  S  0                                          5.194                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  S  2                                          5.195                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  S  0                                          5.196                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  S  2                                          5.197                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  S  0                                          5.198                                                                             H  H  H  CH.sub.3                                                                          H A  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  S  2                                          5.199                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  S  0                                          5.200                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  S  2                                          5.201                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  S  0                                          5.202                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  S  2                                          5.203                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  S  0                                          5.204                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  S  2                                          5.205                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  S  0                                          5.206                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  S  2                                          5.207                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  S  0                                          5.208                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  S  2                                          5.209                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl S  0                                          5.210                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl S  2                                          5.211                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl S  0                                          5.212                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl S  2                                          5.213                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl S  0                                          5.214                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl S  2                                          5.215                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl S  0                                          5.216                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl S  2                                          5.217                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.218                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.219                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.220                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.221                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.222                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.223                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.224                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.225                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  S  0                                          5.226                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  S  2                                          5.227                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  S  0                                          5.228                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  S  2                                          5.229                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  S  0                                          5.230                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  S  2                                          5.231                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  S  0                                          5.232                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          H  S  2                                          5.233                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  SO.sub.2                                                                          0                                          5.234                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  SO.sub.2                                                                          2                                          5.235                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  SO.sub.2                                                                          0                                          5.236                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  SO.sub.2                                                                          2                                          5.237                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  SO.sub.2                                                                          0                                          5.238                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  SO.sub.2                                                                          2                                          5.239                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  SO.sub.2                                                                          0                                          5.240                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  SO.sub.2                                                                          2                                          5.241                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.242                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.243                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.244                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.245                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.246                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.247                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.248                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.249                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          0                                          5.250                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          2                                          5.251                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          0                                          5.252                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          2                                          5.253                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          0                                          5.254                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          2                                          5.255                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          0                                          5.256                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          2                                          5.257                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          0                                          5.258                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          2                                          5.259                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          0                                          5.260                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          2                                          5.261                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          0                                          5.262                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          2                                          5.263                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          0                                          5.264                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          2                                          5.265                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.266                                                                             H  H  H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          5.267                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.268                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          5.269                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.270                                                                             H  H  H  CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          5.271                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.272                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          5.273                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  O  0                                          5.274                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  O  2                                          5.275                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  O  0                                          5.276                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH H  CH.sub.3                                                                          H   H  O  2                                          5.277                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  O  0                                          5.278                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  O  2                                          5.279                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  O  0                                          5.280                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  O  2                                          5.281                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  O  0                                          5.282                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  O  2                                          5.283                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  O  0                                          5.284                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  O  2                                          5.285                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  O  0                                          5.286                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  O  2                                          5.287                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  O  0                                          5.288                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  O  2                                          5.289                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  O  0                                          5.290                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  O  2                                          5.291                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  O  0                                          5.292                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  O  2                                          5.293                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  O  0                                          5.294                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  O  2                                          5.295                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  O  0                                          5.296                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  O  2                                          5.297                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl O  0                                          5.298                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl O  2                                          5.299                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl O  0                                          5.300                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl O  2                                          5.301                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl O  0                                          5.302                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl O  2                                          5.303                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl O  0                                          5.304                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl O  2                                          5.305                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.306                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.307                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.308                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.309                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.310                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.311                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  0                                          5.312                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          O  2                                          5.313                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  O  0                                          5.314                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  O  2                                          5.315                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  O  0                                          5.316                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  O  2                                          5.317                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  O  0                                          5.318                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  O  2                                          5.319                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  O  0                                          5.320                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  O  2                                          5.321                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  S  0                                          5.322                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  S  2                                          5.323                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  S  0                                          5.324                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  S  2                                          5.325                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  S  0                                          5.326                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  S  2                                          5.327                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  S  0                                          5.328                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  S  2                                          5.329                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  S  0                                          5.330                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  S  2                                          5.331                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  S  0                                          5.332                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  S  2                                          5.333                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  S  0                                          5.334                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  S  2                                          5.335                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  S  0                                          5.336                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  S  2                                          5.337                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  S  0                                          5.338                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  S  2                                          5.339                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  S  0                                          5.340                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  S  2                                          5.341                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  S  0                                          5.342                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  S  2                                          5.343                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  S  0                                          5.344                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  S  2                                          5.345                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl S  0                                          5.346                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl S  2                                          5.347                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl S  0                                          5.348                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl S  2                                          5.349                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl S  0                                          5.350                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl S  2                                          5.351                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl S  0                                          5.352                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl S  2                                          5.353                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.354                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.355                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.356                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.357                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.358                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.359                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  0                                          5.360                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          S  2                                          5.361                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  S  0                                          5.362                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  S  2                                          5.363                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  S  0                                          5.364                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  S  2                                          5.365                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  S  0                                          5.366                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  S  2                                          5.367                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  S  0                                          5.368                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          H  S  2                                          5.369                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  SO.sub.2                                                                          0                                          5.370                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  SO.sub.2                                                                          2                                          5.371                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  SO.sub.2                                                                          0                                          5.372                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  SO.sub.2                                                                          2                                          5.373                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  SO.sub.2                                                                          0                                          5.374                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  SO.sub.2                                                                          2                                          5.375                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  SO.sub.2                                                                          0                                          5.376                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          H   H  SO.sub.2                                                                          2                                          5.377                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.378                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.379                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.380                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.381                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.382                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.383                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          0                                          5.384                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H  SO.sub.2                                                                          2                                          5.385                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          0                                          5.386                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          2                                          5.387                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          0                                          5.388                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          2                                          5.389                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          0                                          5.390                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          2                                          5.391                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          0                                          5.392                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H  SO.sub.2                                                                          2                                          5.393                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          0                                          5.394                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          2                                          5.395                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          0                                          5.396                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          2                                          5.397                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          0                                          5.398                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          2                                          5.399                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          0                                          5.400                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl SO.sub.2                                                                          2                                          5.401                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.402                                                                             H  H  H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          5.403                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.404                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H  H  H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          5.405                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.406                                                                             H  H  H  CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          5.407                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          0                                          5.408                                                                             H  H  CH.sub.3                                                                          CH.sub.3                                                                          H CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          SO.sub.2                                                                          2                                          __________________________________________________________________________

                                      TABLE 6                                      __________________________________________________________________________      ##STR19##                                                                     No.                                                                               R.sup.5                                                                           R.sup.6                                                                           R.sup.7                                                                            R.sup.8                                                                           R.sup.1                                                                           R.sup.4                                                                           M   L   X  n                                             __________________________________________________________________________     6.1                                                                               H  H  H   H  H  CH.sub.3                                                                          H   H   O  0                                             6.2                                                                               H  H  H   H  H  CH.sub.3                                                                          H   H   O  2                                             6.3                                                                               CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          H   H   O  0                                             6.4                                                                               CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          H   H   O  2                                             6.5                                                                               H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   O  0                                             6.6                                                                               H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   O  2                                             6.7                                                                               H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   O  0                                             6.8                                                                               H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   O  2                                             6.9                                                                               H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   O  0                                             6.10                                                                              H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   O  2                                             6.11                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   O  0                                             6.12                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   O  2                                             6.13                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   O  0                                             6.14                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   O  2                                             6.15                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   O  0                                             6.16                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   O  2                                             6.17                                                                              H  H  H   H  H  CH.sub.3                                                                          Cl  H   O  0                                             6.18                                                                              H  H  H   H  H  CH.sub.3                                                                          Cl  H   O  2                                             6.19                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  H   O  0                                             6.20                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  H   O  2                                             6.21                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   O  0                                             6.22                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   O  2                                             6.23                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   O  0                                             6.24                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   O  2                                             6.25                                                                              H  H  H   H  H  CH.sub.3                                                                          Cl  Cl  O  0                                             6.26                                                                              H  H  H   H  H  CH.sub.3                                                                          Cl  Cl  O  2                                             6.27                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  Cl  O  0                                             6.28                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  Cl  O  2                                             6.29                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  O  0                                             6.30                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  O  2                                             6.31                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  O  0                                             6.32                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  O  2                                             6.33                                                                              H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.34                                                                              H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.35                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.36                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.37                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.38                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.39                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.40                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.41                                                                              H  H  H   H  H  CH.sub.3                                                                          H   H   S  0                                             6.42                                                                              H  H  H   H  H  CH.sub.3                                                                          H   H   S  2                                             6.43                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          H   H   S  0                                             6.44                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          H   H   S  2                                             6.45                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   S  0                                             6.46                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   S  2                                             6.47                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   S  0                                             6.48                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   S  2                                             6.49                                                                              H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   S  0                                             6.50                                                                              H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   S  2                                             6.51                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   S  0                                             6.52                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   S  2                                             6.53                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   S  0                                             6.54                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   S  2                                             6.55                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   S  0                                             6.56                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   S  2                                             6.57                                                                              H  H  H   H  H  CH.sub.3                                                                          Cl  H   S  0                                             6.58                                                                              H  H  H   H  H  CH.sub.3                                                                          Cl  H   S  2                                             6.59                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  H   S  0                                             6.60                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  H   S  2                                             6.61                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   S  0                                             6.62                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   S  2                                             6.63                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   S  0                                             6.64                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   S  2                                             6.65                                                                              H  H  H   H  H  CH.sub.3                                                                          Cl  Cl  S  0                                             6.66                                                                              H  H  H   H  H  CH.sub.3                                                                          Cl  Cl  S  2                                             6.67                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  Cl  S  0                                             6.68                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  Cl  S  2                                             6.69                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  S  0                                             6.70                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  S  2                                             6.71                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  S  0                                             6.72                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  S  2                                             6.73                                                                              H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.74                                                                              H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.75                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.76                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.77                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.78                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.79                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.80                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.81                                                                              H  H  H   H  H  CH.sub.3                                                                          H   H   SO.sub.2                                                                          0                                             6.82                                                                              H  H  H   H  H  CH.sub.3                                                                          H   H   SO.sub.2                                                                          2                                             6.83                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          H   H   SO.sub.2                                                                          0                                             6.84                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          H   H   SO.sub.2                                                                          2                                             6.85                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   SO.sub.2                                                                          0                                             6.86                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   SO.sub.2                                                                          2                                             6.87                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   SO.sub.2                                                                          0                                             6.88                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          H   H   SO.sub.2                                                                          2                                             6.89                                                                              H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.90                                                                              H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.91                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.92                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.93                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.94                                                                              H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.95                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.96                                                                              H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.97                                                                              H  H  H   H  H  CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          0                                             6.98                                                                              H  H  H   H  H  CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          2                                             6.99                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          0                                             6.100                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          2                                             6.101                                                                             H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          0                                             6.102                                                                             H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          2                                             6.103                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          0                                             6.104                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          2                                             6.105                                                                             H  H  H   H  H  CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          0                                             6.106                                                                             H  H  H   H  H  CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          2                                             6.107                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          0                                             6.108                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          2                                             6.109                                                                             H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          0                                             6.110                                                                             H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          2                                             6.111                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          pard 0                                        6.112                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          2                                             6.113                                                                             H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.114                                                                             H  H  H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                             6.115                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.116                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                             6.117                                                                             H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.118                                                                             H  H  H   CH.sub.3                                                                          H  CH.sub.3                                                                          CCH.sub.3                                                                          CH.sub.3                                                                           SO.sub.2                                                                          2                                             6.119                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.120                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                             6.121                                                                             H  H  H   H  CH.sub.3                                                                          H  H   H   O  0                                             6.122                                                                             H  H  H   H  CH.sub.3                                                                          H  H   H   O  2                                             6.123                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  H   H   O  0                                             6.124                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  H   H   O  2                                             6.125                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   O  0                                             6.126                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   O  2                                             6.127                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   O  0                                             6.128                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   O  2                                             6.129                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   O  0                                             6.130                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   O  2                                             6.131                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   O  0                                             6.132                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   O  2                                             6.133                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   O  0                                             6.134                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   O  2                                             6.135                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   O  0                                             6.136                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   O  2                                             6.137                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  H   O  0                                             6.138                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  H   O  2                                             6.139                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  H   O  0                                             6.140                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  H   O  2                                             6.141                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   O  0                                             6.142                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   O  2                                             6.143                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   O  0                                             6.144                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   O  2                                             6.145                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  Cl  O  0                                             6.146                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  Cl  O  2                                             6.147                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  Cl  O  0                                             6.148                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  Cl  O  2                                             6.149                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  O  0                                             6.150                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  O  2                                             6.151                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  O  0                                             6.152                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  O  2                                             6.153                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.154                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.155                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.156                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.157                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.158                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.159                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.160                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.161                                                                             H  H  H   H  CH.sub.3                                                                          H  H   H   S  0                                             6.162                                                                             H  H  H   H  CH.sub.3                                                                          H  H   H   S  2                                             6.163                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  H   H   S  0                                             6.164                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  H   H   S  2                                             6.165                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   S  0                                             6.166                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   S  2                                             6.167                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   S  0                                             6.168                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   S  2                                             6.169                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   S  0                                             6.170                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   S  2                                             6.171                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   S  0                                             6.172                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   S  2                                             6.173                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   S  0                                             6.174                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   S  2                                             6.175                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   S  0                                             6.176                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   S  2                                             6.177                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  H   S  0                                             6.178                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  H   S  2                                             6.179                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  H   S  0                                             6.180                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  H   S  2                                             6.181                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   S  0                                             6.182                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   S  2                                             6.183                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   S  0                                             6.184                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   S  2                                             6.185                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  Cl  S  0                                             6.186                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  Cl  S  2                                             6.187                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  Cl  S  0                                             6.188                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  Cl  S  2                                             6.189                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  S  0                                             6.190                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  S  2                                             6.191                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  S  0                                             6.192                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  S  2                                             6.193                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.194                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.195                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.196                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.197                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.198                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.199                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.200                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.201                                                                             H  H  H   H  CH.sub.3                                                                          H  H   H   SO.sub.2                                                                          0                                             6.202                                                                             H  H  H   H  CH.sub.3                                                                          H  H   H   SO.sub.2                                                                          2                                             6.203                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  H   H   SO.sub.2                                                                          0                                             6.204                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  H   H   SO.sub.2                                                                          2                                             6.205                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   SO.sub.2                                                                          0                                             6.206                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   SO.sub.2                                                                          2                                             6.207                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   SO.sub.2                                                                          0                                             6.208                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  H   H   SO.sub.2                                                                          2                                             6.209                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.210                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.211                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.212                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.213                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.214                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.215                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.216                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.217                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  H   SO.sub.2                                                                          0                                             6.218                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  H   SO.sub.2                                                                          2                                             6.219                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  H   SO.sub.2                                                                          0                                             6.220                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  H   SO.sub.2                                                                          2                                             6.221                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   SO.sub.2                                                                          0                                             6.222                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   SO.sub.2                                                                          2                                             6.223                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   SO.sub.2                                                                          0                                             6.224                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  H   SO.sub.2                                                                          2                                             6.225                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  Cl  SO.sub.2                                                                          0                                             6.226                                                                             H  H  H   H  CH.sub.3                                                                          H  Cl  Cl  SO.sub.2                                                                          2                                             6.227                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  Cl  SO.sub.2                                                                          0                                             6.228                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  Cl  Cl  SO.sub.2                                                                          2                                             6.229                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  SO.sub.2                                                                          0                                             6.230                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  SO.sub.2                                                                          2                                             6.231                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  SO.sub.2                                                                          0                                             6.232                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  Cl  Cl  SO.sub.2                                                                          2                                             6.233                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.234                                                                             H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                             6.235                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.236                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                             6.237                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.238                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                             6.239                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.240                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                             6.241                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   O  0                                             6.242                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   O  2                                             6.243                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   O  0                                             6.244                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   O  2                                             6.245                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   O  0                                             6.246                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   O  2                                             6.247                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   O  0                                             6.248                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   O  2                                             6.249                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   O  0                                             6.250                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   O  2                                             6.251                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   O  0                                             6.252                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   O  2                                             6.253                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   O  0                                             6.254                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   O  2                                             6.255                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   O  0                                             6.256                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   O  2                                             6.257                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   O  0                                             6.258                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   O  2                                             6.259                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   O  0                                             6.260                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   O  2                                             6.261                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   O  0                                             6.262                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   O  2                                             6.263                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   O  0                                             6.264                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   O  2                                             6.265                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  O  0                                             6.266                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  O  2                                             6.267                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  O  0                                             6.268                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  O  2                                             6.269                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  O  0                                             6.270                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  O  2                                             6.271                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  O  0                                             6.272                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  O  2                                             6.273                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.274                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.275                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.276                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.277                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.278                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.279                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  0                                             6.280                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           O  2                                             6.281                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   S  0                                             6.282                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   S  2                                             6.283                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   S  0                                             6.284                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   S  2                                             6.285                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   S  0                                             6.286                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   S  2                                             6.287                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   S  0                                             6.288                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   S  2                                             6.289                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   S  0                                             6.290                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   S  2                                             6.291                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   S  0                                             6.292                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   S  2                                             6.293                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   S  0                                             6.294                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   S  2                                             6.295                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   S  0                                             6.296                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   S  2                                             6.297                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   S  0                                             6.298                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   S  2                                             6.299                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   S  0                                             6.300                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   S  2                                             6.301                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   S  0                                             6.302                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   S  2                                             6.303                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   S  0                                             6.304                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   S  2                                             6.305                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  S  0                                             6.306                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  S  2                                             6.307                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  S  0                                             6.308                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  S  2                                             6.309                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  S  0                                             6.310                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  S  2                                             6.311                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  S  0                                             6.312                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  S  2                                             6.313                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.314                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.315                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.316                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.317                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.318                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.319                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  0                                             6.320                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           S  2                                             6.321                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   SO.sub.2                                                                          0                                             6.322                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   SO.sub.2                                                                          2                                             6.323                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   SO.sub.2                                                                          0                                             6.324                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          H   H   SO.sub.2                                                                          2                                             6.325                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   SO.sub.2                                                                          0                                             6.326                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   SO.sub.2                                                                          2                                             6.327                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   SO.sub.2                                                                          0                                             6.328                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H   SO.sub.2                                                                          2                                             6.329                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.330                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.331                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.332                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.333                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.334                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.335                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          0                                             6.336                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   SO.sub.2                                                                          2                                             6.337                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          0                                             6.338                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          2                                             6.339                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          0                                             6.340                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          2                                             6.341                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          0                                             6.342                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          2                                             6.343                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          0                                             6.344                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  H   SO.sub.2                                                                          2                                             6.345                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          0                                             6.346                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          2                                             6.347                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          0                                             6.348                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          2                                             6.349                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          0                                             6.350                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          2                                             6.351                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          0                                             6.352                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          Cl  Cl  SO.sub.2                                                                          2                                             6.353                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.354                                                                             H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                             6.355                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.356                                                                             CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                             6.357                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.358                                                                             H  H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                             6.359                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          0                                             6.360                                                                             H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           SO.sub.2                                                                          2                                             __________________________________________________________________________

PREPARATION EXAMPLES

A) Preparation Examples for the starting materials and intermediates

1. Ethyl 3-(2-bromoethoxy)-2-methylbenzoate

13.6 g (0.2 mol) of sodium methoxide are dissolved in 200 ml of ethanol. 36 g (0.2 mol) of ethyl 3-hydroxy-2-methylbenzoate are then added and the mixture is refluxed for 2 hours. 61.4 g (0.32 mol) of 1,2-dibromoethane are then added dropwise and the mixture is heated to reflux for 20 hours. The cooled reaction mixture is concentrated on a rotary evaporator. The residue is taken up with ethyl acetate and washed 3 times with dilute sodium hydroxide solution. The organic phase is dried and the solvent is distilled off. The useful product is purified by column chromatography. Yield: 14.6 g of oil

NMR(270 MHZ; CDCl₃ ; δ in ppm): 7.4 (d, 1H), 7.2 (tr, 1H), 6.9 (d, 1H), 4.4 (tr, 2H), 4.3 (q, 2H), 3.7 (tr, 2H), 2.4 (s, 3H), 1.5 (tr, 3H)

2. Ethyl 3-(2-methylsulfonylthioethoxy)-2-methylbenzoate

2 g (7 mmol) of ethyl 3-(2-bromoethoxy)-2-methylbenzoate and 1.1 g (7.3 mmol) of potassium thiomethanesulfonate are dissolved in 10 ml of abs. ethanol. The reaction mixture is refluxed for 20 hours. The solvent is then distilled off and the residue is taken up in methylene chloride and washed with water. The organic phase is dried over sodium sulfate and the solvent is removed. The useful product is purified by column chromatography.

Yield 1.1 g (50%)

NMR(270 MHZ; CDCl₃ ; δ in ppm): 7.4 (d, 1H), 7.2 (tr, 1H), 7.0 (d, 1H), 4.5 (tr, 2H), 4.3 (q, 2H), 3.6 (tr, 2H), 3.4 (s, 3H), 2.4 (s, 3H), 1.4 (tr, 3H)

3. Ethyl 8-methyl-2,3-dihydrobenz-1,4-oxathiin-7-carboxylate

1.0 g (3.4 mmol) of ethyl 3-(2-methylsulfonylthioethoxy)-2-methylbenzoate are dissolved in 5 ml of nitromethane. 0.42 g (3.14 mmol) of aluminum trichloride is added. The mixture is stirred at room temperature for 45 min. Working-up is carried out by addition of 10 ml of 2N hydrochloric acid and subsequent extraction with MTB ether. The combined organic phases are washed with water and sodium carbonate solution, dried over sodium sulfate and the solvent is distilled off.

Yield: 0.7 g (93%)

NMR(270 MHZ; CDCl₃ ; δ in ppm): 7.5 (d, 1H), 6.9 (d, 1H), 4.5 (tr, 2H), 4.3 (q, 2H), 3.2 (tr, 2H), 2.4 (s, 3H), 1.4 (tr, 3H),

4. 8-Methyl-2,3-dihydrobenz-1,4-oxathiin-7-carboxylic acid

4.0 g (0.0168 mol) of ethyl 8-methyl-2,3-dihydrobenz-1,4-oxathiin-7-carboxylate are heated to reflux together with 1.0 g (0.0252 mol) of sodium hydroxide in 40 ml of methanol/water. The mixture is stirred for 2 hours at the room temperature and the solvent is then distilled off. The residue is taken up with water. The mixture is extracted with ether and the aqueous phase is then acidified with 2N hydrochloric acid. The useful product precipitates, is filtered off with suction and washed with a little water. The product is dried in a vacuum drying oven at 40° C.

Yield: 2.9 g (82%)

NMR(270 MHZ; d⁶ -DMSO; δ in ppm): 12.3 (bs, 1H), 7.3 (d, 1H) 6.9 (d, 1H), 4.4 (tr, 2H), 3.2 (tr, 2H), 2.4 (s, 3H),

5. 8-Methyl-2,3-dihydro-4,4-dioxobenz-1,4-oxythiin-7-carboxylic acid

2.8 g (0.013 mol) of 8-methyl-2,3-dihydrobenz-1,4-oxathiin-7-carboxylic acid are initially introduced together with a spatula tipful of sodium tungstate in 30 ml of acetic acid.

The mixture is heated to 50° C. 3.3 g (0.029 mol) of hydrogen peroxide (30% strength) are added dropwise. The reaction solution is kept at 50-60° C. for a further 4 hours. The solution is added to ice-water. The precipitate is filtered off with suction, washed with water and dried in a vacuum drying oven at 40° C.

Yield: 2.7 g

Melting point: 234° C.

                                      TABLE 7                                      __________________________________________________________________________                                        III                                          ##STR20##                                                                     No.                                                                               T   R.sup.1                                                                          R.sup.2                                                                           R.sup.3                                                                          R.sup.4                                                                          X  M   L n Phys. data                                          __________________________________________________________________________     7.1                                                                               OC.sub.2 H.sub.5                                                                   H H  H H O  CH.sub.3                                                                           H 0 1H-NMR(270 MHz;                                                                CDCl.sub.3 ; in ppm): 7.5                                                      (d, 1H), 6.9(d, 1H),                                                           4.5(tr, 2H), 4.3(q,                                                            2H), 3.2(tr, 2H), 2.4                                                          (s, 3H), 1.4(tr, 3H)                                7.2                                                                               HO  H H  H H O  CH.sub.3                                                                           H 0 1H-NMR(270 MHz;                                                                d.sup.6 -DMSO; in ppm):                                                        12.3(bs, 1H), 7.3(d,                                                           1H), 6.9(d, 1H), 4.4                                                           (tr, 2H), 3.2(tr, 2H),                                                         2.4(s, 3H)                                          7.3                                                                               HO  H H  H H O  CH.sub.3                                                                           H 2 M.p.[° C.]: 234                              7.4                                                                               OCH.sub.3                                                                          H H  H H S  CH.sub.3                                                                           H 0 M.p.[° C.]: 57                               7.5                                                                               OH  H H  H H S  CH.sub.3                                                                           H 0 M.p.[° C.]: 179                              7.6                                                                               OH  H H  H H SO.sub.2                                                                          CH.sub.3                                                                           H 2 1H-NMR(250 MHz,                                                                d.sup.6 -DMSO): 13.8(bs),                                                      8.11(d), 7.98(d),                                                              4.40(m), 2.80(s)                                    7.7                                                                               OC.sub.2 H.sub.5                                                                   H H  H H O  Cl  H 0 1H-NMR(CDCl.sub.3):                                                            7.3(2x d), 4.4(q),                                                             4.5(tr), 3.2(tr), 1.4                                                          (tr)                                                7.8                                                                               OH  H H  H H O  Cl  H 0 M.p.[° C.]: 209° C.                   7.9                                                                               OH  H H  H H O  Cl  H 2 M.p.[° C.]: 225                              __________________________________________________________________________

                  TABLE 8                                                          ______________________________________                                          ##STR21##                                                                     No.  T       R.sup.1                                                                               R.sup.4                                                                            X   M     L   n   Phys. data                           ______________________________________                                         8.1  OC.sub.2 H.sub.5                                                                       H      H   O   CH.sub.3                                                                             H   0   1H-NMR(270 MHz;                                                                CDCl.sub.3 : 7.44(d),                                                          6.85(d), 6.50(d),                                                              5.25(d), 4.32(q),                                                              2.36(s), 1.36(tr)                    8.2  OH      H      H   O   CH.sub.3                                                                             H   0   M.p.[° C.]: 174               8.3  OH      H      H   O   CH.sub.3                                                                             H   2   M.p.[° C.]: 205               8.4  OC.sub.2 H.sub.5                                                                       H      H   O   Cl    H   0   M.p.[° C.]: 92                8.5  OH      H      H   O   Cl    H   0   M.p.[° C.]:                   ______________________________________                                                                                   201                             

Preparation of the final products

1. 2-(8-Methyl-2,3-dihydro-4,4-dioxobenz-1,4-oxathiin-7-carbonyl)-1,3-cyclohexanedione

0.9 g (3.72 mmol) of 8-methyl-2,3-dihydro-4,4-dioxobenz-1,4-oxathiin-7-carboxylic acid and 0.42 g (3.72 mmol) of 1,3-cyclohexadione are dissolved in 20 ml of acetonitrile. 0.81 g (3.9 mmol) of DCC (dicyclohexylcarbodiimide) is then added and the mixture is stirred for several hours until it has reacted completely. 0.75 g (7.44 mmol) of triethylamine and 0.2 ml of trimethylsilyl cyanide are then added dropwise. The mixture is stirred at RT for 3 hours. For working-up, the reaction mixture is poured into 100 ml of 2% strength sodium carbonate solution. The precipitate is filtered off with suction and the aqueous phase is washed with ethyl acetate. The aqueous phase is then acidified with 2N hydrochloric acid. The useful product precipitates. It is filtered off with suction, washed with water and dried in a vacuum drying oven.

Yield: 0.6 g

Melting point: 201° C.

                                      TABLE 9                                      __________________________________________________________________________      ##STR22##                                                                     No.                                                                               R.sup.1                                                                          R.sup.2                                                                          R.sup.3                                                                          R.sup.4                                                                          R.sup.5                                                                           R.sup.6                                                                           R.sup.7                                                                           R.sup.8                                                                           X  M  L n Phys. data                                    __________________________________________________________________________     9.1                                                                               H H H H H  H  H  H  O  CH.sub.3                                                                          H 2 M.p.[° C.]:                                                             201                                           9.2                                                                               H H H H H  H  CH.sub.3                                                                          CH.sub.3                                                                          O  CH.sub.3                                                                          H 2 M.p.[° C.]:                                                             177                                           9.3                                                                               H H H H H  H  H  H  O  CH.sub.3                                                                          H 0 M.p.[° C.]:                                                             110                                           9.4                                                                               H H H H H  H  CH.sub.3                                                                          CH.sub.3                                                                          O  CH.sub.3                                                                          H 0 M.p.[° C.]:                                                             114                                           9.5                                                                               H H H H CH.sub.3                                                                          CH.sub.3                                                                          H  H  O  CH.sub.3                                                                          H 0 M.p.[° C.]: 78                         9.6                                                                               H H H H H  H  H  H  SO.sub.2                                                                          CH.sub.3                                                                          H 2 M.p.[° C.]:                                                             239                                           9.7                                                                               H H H H H  H  CH.sub.3                                                                          H  SO.sub.2                                                                          CH.sub.3                                                                          H 2 M.p.[° C.]:                                                             207                                           9.8                                                                               H H H H H  H  CH.sub.3                                                                          CH.sub.3                                                                          SO.sub.2                                                                          CH.sub.3                                                                          H 2 M.p.[° C.]:                                                             243                                           9.9                                                                               H H H H CH.sub.3                                                                          CH.sub.3                                                                          H  H  SO.sub.2                                                                          CH.sub.3                                                                          H 2 M.p.[° C.]:                                                             147                                           9.10                                                                              H H H H H  H  H  H  S  CH.sub.3                                                                          H 0 M.p.[° C.]:                                                             128                                           9.11                                                                              H H H H H  H  CH.sub.3                                                                          CH.sub.3                                                                          S  CH.sub.3                                                                          H 0 M.p.[° C.]: 54                         9.12                                                                              H H H H CH.sub.3                                                                          CH.sub.3                                                                          H  H  S  CH.sub.3                                                                          H 0 M.p.[° C.]: 63                         9.13                                                                              H H H H H  H  H  H  O  Cl H 0 M.p.[° C.]:                                                             135                                           9.14                                                                              H H H H H  H  CH.sub.3                                                                          CH.sub.3                                                                          O  Cl H 0 M.p.[° C.]: 66                         __________________________________________________________________________

                                      TABLE 10                                     __________________________________________________________________________      ##STR23##                                                                     No.                                                                               R.sup.5                                                                           R.sup.6                                                                           R.sup.7                                                                           R.sup.8                                                                           R.sup.1                                                                          R.sup.4                                                                          X M  L n Phys. data                                         __________________________________________________________________________     10.1                                                                              H  H  H  H  H H O CH.sub.3                                                                          H 0 M.p.[° C.]: 94                              10.2                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H O CH.sub.3                                                                          H 0 1H-NMR(270 MHz,                                                                CDCl.sub.3): 17.6(bs), 6.71                                                    (m), 6.46(d), 5.23(d),                                                         2.65(s), 2.33(s), 2.03(s),                                                     1.12(s)                                            10.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H O CH.sub.3                                                                          H 0 1H-NMR(270 MHz,                                                                CDCl.sub.3, isomer mixture):                                                   17,45(g), 6.78(d), 6.68                                                        (d), 6.47(d), 5.21(d),                                                         2.80(m), 1.99(s), 1.89                                                         (m), 1.18(s)                                                                   and                                                                            18.0(s), 6.78(d), 6.68                                                         (d), 6.48(d), 5.22(d),                                                         2.47(m), 2.21(s), 1.89                                                         (m), 1.38(s)                                       10.4                                                                              H  H  H  H  H H O CH.sub.3                                                                          H 2 M.p.[° C.]: 245                             10.5                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H O CH.sub.3                                                                          H 2 M.p.[° C.]: 216                             10.6                                                                              CH.sub.3                                                                          CH.sub.3                                                                          H  H  H H O CH.sub.3                                                                          H 2 M.p.[° C.]: 107                             10.7                                                                              H  H  H  H  H H O Cl H 0 M.p.[° C.]: 108                             10.8                                                                              H  H  CH.sub.3                                                                          CH.sub.3                                                                          H H O Cl H 0 M.p.[° C.]: 56                              __________________________________________________________________________

The compounds I and their agriculturally utilizable salts are suitable, both as isomer mixtures and in the form of the pure isomers, as herbicides. The herbicidal compositions comprising I control plant growth on uncultivated areas very well, particularly at high application rates. In crops such as wheat, rice, maize, soybeans and cotton, they act against broad-leaved weeds and grass weeds without noticeably damaging the crop plants. This effect occurs especially at low application rates.

Depending on the particular application method, the compounds I or compositions containing them can additionally be employed for eliminating undesired plants in a further number of crop plants. Suitable crops are, for example, the following:

Allium cepa, Ananas comosus, Arachis hypogaea, Asparagus officinalis, Beta vulgaris spp. altissima, Beta vulagris spp. rapa, Brassica napus var. napus, Brassica napus var. napobrassica, Brassica rapa var. silvestris, Camellia sinensis, Carthamus tinctorius, Carya illinoinensis, Citrus limon, Citrus sinensis, Coffea arabica (Coffea canephora, Coffea liberica), Cucumis sativus, Cynodon dactylon, Daucus carota, Elaeis guineensis, Fragaria vesca, Glycine max, Gossypium hirsutum, (Gossypium arboreum, Gossypium herbaceum, Gossypium vitifolium), Helianthus annuus, Hevea brasiliensis, Hordeum vulgare, Humulus lupulus, Ipomoea batatas, Juglans regia, Lens culinaris, Linum usitatissimum, Lycopersicon lycopersicum, Malus spp., Manihot esculenta, Medicago sativa, Musa spp., Nicotiana tabacum (N.rustica), Olea europaea, Oryza sativa, Phaseolus lunatus, Phaseolus vulgaris, Picea abies, Pinus spp., Pisum sativum, Prunus avium, Prunus persica, Pyrus communis, Ribes sylestre [sic], Ricinus communis, Saccharum officinarum, Secale cereale, Solanum tuberosum, Sorghum bicolor (s. vulgare), Theobroma cacao, Trifolium pratense, Triticum aestivum, Triticum durum, Vicia faba, Vitis vinifera, Zea mays.

Moreover, the compounds I can also be used in crops which as a result of breeding, including genetic engineering methods, are tolerant to the action of herbicides.

The application of the herbicidal compositions or of the active compounds can be carried out pre-emergence or post-emergence. If the active substances are less tolerable for certain crop plants, application techniques can be used in which the herbicidal compositions are sprayed with the aid of spray equipment such that the leaves of the sensitive crop plants are not affected if possible, while the active compounds reach the leaves of undesired plants growing under them or the uncovered soil surface (post-directed, lay-by).

The compounds I or the herbicidal compositions comprising them an be used, for example, in the form of directly sprayable aqueous solutions, powders, suspensions, even high-percentage aqueous, oily or other suspensions or dispersions, emulsions, oil dispersions, pastes, dusting compositions, broadcasting compositions or granules, by spraying, atomizing, dusting, broadcasting or watering. The application forms depend on the intended uses; they should in each case if possible guarantee the finest dispersion of the active compounds according to the invention.

Suitable inert additives are essentially: mineral oil fractions of medium to high boiling point, such as kerosene or diesel oil, also coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, eg. paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, alkylated benzenes or their derivatives, alcohols such as methanol, ethanol, propanol, butanol, cyclohexanol, ketones such as cyclohexanone or strongly polar solvents, eg. amines such as N-methylpyrrolidone or water.

Aqueous application forms can be prepared from emulsion concentrates, suspensions, pastes, wettable powders or water-dispersible granules by addition of water. To prepare emulsions, pastes or oil dispersions, the substrates [sic], as such or dissolved in an oil or solvent, can be homogenized in water by means of wetting agents, adherents, dispersants or emulsifiers. However, concentrates consisting of active substance, wetting agent, adherent, dispersant or emulsifier and possibly solvent or oil can also be prepared, which are suitable for dilution with water.

Suitable surface-active substances (adjuvants) are the alkali metal, alkaline earth metal and ammonium salts of aromatic sulfonic acids, eg. lignosulfonic, phenolsulfonic, naphthalenesulfonic and dibutylnaphthalenesulfonic acid, and also of fatty acids, alkyl- and alkylarylsulfonates, alkyl, lauryl ether and fatty alcohol sulfates, as well as salts of sulfated hexa-, hepta- and octadecanols and also of fatty alcohol glycol ethers, condensation products of sulfonated naphthalene and its derivatives with formaldehyde, condensation products of naphthalene or of the naphthalenesulfonic acids with phenol and formaldehyde, polyoxyethylene octylphenol ethers, ethoxylated isooctyl-, octyl- or nonylphenol, alkylphenyl and tributylphenyl polyglycol ethers, alkylaryl polyether alcohols, isotridecyl alcohol, fatty alcohol-ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers or polyoxypropylene alkyl ethers, lauryl alcohol polyglycol ether acetate, sorbitol esters, lignin-sulfite waste liquors or methylcellulose.

Powder, broadcasting and dusting compositions can be prepared by mixing or joint grinding of the active substances with a solid carrier.

Granules, eg. coated, impregnated and homogeneous granules, can be prepared by binding the active compounds to solid carriers. Solid carriers are mineral earths such as silicic acids, silica gels, silicates, talc, kaolin, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products such as cereal flour, tree bark, wood and nutshell meal, cellulose powder or other solid carriers.

The concentrations of the active compounds I in the ready-to-use preparations can be varied within wide ranges. The formulations in general contain from 0.001 to 98% by weight, preferably 0.01 to 95% by weight, of active compound. The active compounds are employed here in a purity of from 90% to 100%, preferably 95% to 100% (according to NMR spectrum).

The compounds I according to the invention can be formulated, for example, as follows:

I. 20 parts by weight of the compound No. 9.1 are dissolved in a mixture which consists of 80 parts by weight of alkylated benzene, 10 parts by weight of the addition product of 8 to mol of ethylene oxide to 1 mol of oleic acid-N-monoethanolamide, 5 parts by weight of calcium salt of dodecylbenzenesulfonic acid and 5 parts by weight of the addition product of 40 mol of ethylene oxide to 1 mol of castor oil. By pouring out the solution and finely dispersing it in 100,000 parts by weight of water, an aqueous dispersion is obtained which contains 0.02% by weight of the active compound.

II. 20 parts by weight of the compound No. 9.1 are dissolved in a mixture which consists of 40 parts by weight of cyclohexanone, 30 parts by weight of isobutanol, 20 parts by weight of the addition product of 40 mol of isooctylphenol and 10 parts by weight of the addition product of 40 mol of ethylene oxide to 1 mol of castor oil. By pouring the solution into and finely dispersing it in 100,000 parts by weight of water, an aqueous dispersion is obtained which contains 0.02% by weight of the active compound.

III. 20 parts by weight of the active compound No. 9.1 are dissolved in a mixture which consists of 25 parts by weight of cyclohexanone, 65 parts by weight of a mineral oil fraction of boiling point 210 to 280° C. and 10 parts by weight of the addition product of 40 mol of ethylene oxide to 1 mol of castor oil. By pouring the solution into and finely dispersing it in 100,000 parts by weight of water, an aqueous dispersion is obtained which contains 0.02% by weight of the active compound.

IV. 20 parts by weight of the active compound No. 9.1 are well mixed with 3 parts by weight of the sodium salt of diisobutylnaphthalenesulfonic acid, 17 parts by weight of the sodium salt of a lignosulfonic acid from a sulfite waste liquor and 60 parts by weight of powdered silica gel and ground in a hammer mill. By finely dispersing the mixture in 20,000 parts by weight of water, a spray mixture is obtained which contains 0.1% by weight of the active compound.

V. 3 parts by weight of the active compound No. 9.1 are mixed with 97 parts by weight of finely divided kaolin. In this manner a broadcasting composition is obtained which contains 3% by weight of the active compound.

VI. 20 parts by weight of the active compound No. 9.1 are intimately mixed with 2 parts by weight of calcium salt of dodecylbenzenesulfonic acid, 8 parts by weight of fatty alcohol polyglycol ether, 2 parts by weight of sodium salt of a phenol-urea-formaldehyde condensate and 68 parts by weight of a paraffinic mineral oil. A stable oily dispersion is obtained.

VII. 1 part by weight of the compound 9.1 is dissolved in a mixture which consists of 70 parts by weight of cyclohexanone, 20 parts by weight of ethoxylated isooctylphenol and 10 parts by weight of ethoxylated castor oil. A stable emulsion concentrate is obtained.

VIII. 1 part by weight of the compound 9.1 is dissolved in a mixture which consists of 80 parts by weight of cyclohexanone and 20 parts by weight of Emulphor EL (ethoxylated caster caster oil). A stable emulsion concentrate is obtained.

To widen the spectrum of action and to achieve synergistic effects, the 2-hetaroylcyclohexane-1,3-diones I can be mixed with numerous representatives of other herbicidal or growth-regulating active compound groups and applied together. For example, suitable mixing components are 1,2,4-thiadiazoles, 1,3,4-thiadiazoles, amides, aminophosphoric acid and its derivatives, aminotriazoles, anilides, (het)aryloxyalkanoic acid and its derivatives, benzoic acid and its derivatives, benzothiadiazinones, 2-aroyl-1,3-cyclohexanediones, hetaryl aryl ketones, benzylisoxazolidinones, meta-CF3-phenyl derivatives, carbamates, quinolinecarboxylic acid and its derivatives, chloroacetanilides, cyclohexane-1,3-dione derivatives, diazines, dichloropropionic acid and its derivatives, dihydrobenzofurans, dihydrofuran-3-ones, dinitroanilines, dinitrophenols, diphenyl ethers, dipyridyls, halocarboxylic acids and their derivatives, ureas, 3-phenyluracils, imidazoles, imidazolinones, N-phenyl-3,4,5,6-tetrahydrophthalimides, oxadiazoles, oxiranes, phenols, aryloxy- and heteroaryloxyphenoxypropionic acid esters, phenylacetic acid and its derivatives, phenylpropionic acid and its derivatives, pyrazoles, phenylpyrazoles, pyridazines, pyridinecarboxylic acid and its derivatives, pyrimidyl ethers, sulfonamides, sulfonylureas, triazines, triazinones, triazolinones, triazolecarboxamides and uracils.

Additionally, it may be useful to apply the compounds I on their own or together in combination with other herbicides, also additionally mixed with further crop protection compositions, for example with compositions for controlling pests or phytopathogenic fungi or bacteria. Furthermore of interest is the miscibility with mineral salt solutions, which are employed for the elimination of nutritional and trace element deficiencies. Nonphytotoxic oils and oil concentrates can also be added.

The application rates of active compound are, depending on the control target, time of year, target plants and stage of growth, from 0.001 to 3.0, preferably 0.01 to 1.0, kg/ha of active substance (a.s.)

Use Examples

It was possible to show the herbicidal action of the 2-hetaroylcyclohexane-1,3-diones of the formula I by greenhouse tests:

The culture vessels used were plastic flowerpots containing loamy sand with about 3.0% humus as a substrate. The seeds of the test plants were sown separately according to species.

In the case of pre-emergence treatment, the active compounds suspended or emulsified in water were applied directly after sowing by means of finely dispersing nozzles. The containers were lightly watered in order to promote germination and growth, and then covered with transparent plastic hoods until the plants had taken root. This covering causes a uniform germination of the test plants, if this has not been adversely affected by the active compounds. The application rate for pre-emergence treatment was 0.0625 or 0.0313 kg/ha of a.s.

For the purpose of post-emergence treatment, the test plants, depending on growth form, are first raised to a growth height of from 3 to 15 cm and only then treated with the active compounds suspended or emulsified in water. For this, the test plants are either sown directly and grown in the same containers or they are first raised separately as seedlings and transplanted into the test containers a few days before treatment.

The plants were kept species-specifically at from 10-25° C. or 20-35° C. The test period extended over 2 to 4 weeks. During this time, the plants were tended, and their reaction to the individual treatments was evaluated.

Assessment was carried out on a scale from 0 to 100. 100 here means no emergence of the plants or complete destruction of at least the above-ground parts and 0 means no damage or normal course of growth.

The plants used in the greenhouse tests were made up of the following species:

    ______________________________________                                         Botanical Name       Common Name                                               ______________________________________                                         Chenopodium album    lamb's-quarters                                           (CHEAL)              (gossefoot [sic])                                         Echinochloa crus-galli                                                                              barnyard grass                                            (ECHCG)                                                                        Solanum nigrum       black nightshade                                          (SOLNI)                                                                        Triticum aestivum    winter wheat                                              (TRZAW)                                                                        Zea mays             Indian corn                                               (ZEAMX)                                                                        ______________________________________                                    

                  TABLE 11                                                         ______________________________________                                         Selective herbicidal activity on post-emergence use                            in a greenhouse                                                                 ##STR24##                                                                     Ex. No. 9.1                                                                    Application rate                                                               (kg/ha of a.s.)  0.0625  0.0313                                                Test plants      Damage in %                                                   ______________________________________                                         TRZAW             0       0                                                    ZEAMX            15       0                                                    ECHCG            90      90                                                    CHEAL            95      95                                                    SOLNI            90      85                                                    ______________________________________                                     

We claim:
 1. A hetaroyl derivative of the formula I ##STR25## where the substituents have the following meanings: L and M hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen, cyano, nitro;X oxygen or sulfur which can be substituted by one or two oxygens; n zero, one, two; R¹ hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen;phenyl which can be monosubstituted or polysubstituted by the following groups: C₁ -C₄ -alkyl, hydrogen, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, nitro, cyano, C₁ -C₄ -alkyloxycarbonyl; R² hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen;phenyl which can be monosubstituted or polysubstituted by the following groups: C₁ -C₄ -alkyl, hydrogen, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, nitro, cyano, C₁ -C₄ -alkyloxycarbonyl; R³ and R² can form a bond; R³ hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen;phenyl which can be monosubstituted or polysubstituted by the following groups: C₁ -C₄ -alkyl, hydrogen, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, nitro, cyano, C₁ -C₄ -alkyloxycarbonyl; R³ and R² can form a bond; R⁴ hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen;phenyl which can be monosubstituted or polysubstituted by the following groups: C₁ -C₄ -alkyl, hydrogen, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, nitro, cyano, C₁ -C₄ -alkyloxycarbonyl; Q a cyclohexane-1,3-dione ring, linked in the 2-position, of the formula II ##STR26## where the substituents have the following meanings: R⁵, R⁶ and R¹⁰ hydrogen, C₁ -C₄ -alkyl; R⁷ hydrogen, C₁ -C₄ -alkyl, C₃ -C₄ -cycloalkyl, it being possible for these groups, if desired, to carry one to three of the following substituents: halogen, C₁ -C₄ -thioalkyl or C₁ -C₄ -alkoxy; or R⁷ C₁ -C₄ -alkoxy; C₁ -C₆ -alkoxyalkyl, tetrahydropyran-3-yl, tetrahydropyran-4-yl; or R⁷ and R⁹ can together form a bond or a three- to six-membered carbocyclic ring; R⁸ hydrogen, C₁ -C₄ -alkyl; R⁹ hydrogen, C₁ -C₄ -alkyl or a group COOR¹¹ ; R¹¹ C₁ -C₄ -alkyl;or agriculturally utilizable salts.
 2. A hetaroyl derivative of the formula Ia ##STR27## where L is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and Q, X, R₁ to R₄ and n have the meanings given in claim
 1. 3. A hetaroyl derivative of the formula Ib ##STR28## where L is C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and Q, X, R₁ to R₄ and n have the meanings given in claim
 1. 4. A hetaroyl derivative of the formula I as defined in claim 1 where the radicals L and M are hydrogen, methyl, methoxy, chlorine, cyano, nitro and trifluoromethyl.
 5. A hetaroyl derivative of the formula Ic ##STR29## where L is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and Q, R₁ to R₄ and n have the meanings given in claim
 1. 6. A hetaroyl derivative of the formula Id ##STR30## where L is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and Q, R₁, R₄ and n have the meanings given in claim
 1. 7. A hetaroyl derivative of the formula Ie ##STR31## where L is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro, and m is zero, one or two and Q, R₁, R₄ and n have the meanings given in claim l.
 8. A hetaroyl derivative of the formula If ##STR32## where L is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro and M is hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, C₁ -C₄ -haloalkyl, C₁ -C₄ -haloalkoxy, halogen, cyano or nitro, and m is zero, one or two and Q, R₁ to R₄ and n have the meanings given in claim
 1. 9. A process for preparing the compound of the formula I as defined in claim 1, which comprises acylating the respective starting substances of the formula II ##STR33## using an acid chloride of the formula IIIa or an acid of the formula IIIb ##STR34## where L, M, X, R¹ to R⁴ and n have the meanings mentioned in claim 1, and rearranging the acylation product to the compounds I in the presence of a catalyst.
 10. A hetaroyl derivative of the formula IIIc ##STR35## where T, L, M, X, R¹ to R⁴ and n have the following meanings: T chlorine, OH or C₁ -C₄ -alkoxy;L hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen, cyano, nitro; M hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen, cyano, nitro; X, R¹, R², R³, R⁴ and n are as given in claim
 1. 11. A hetaroyl derivative of the formula IIId ##STR36## where T, L, M, X, R¹ to R⁴ and n have the following meanings: T chlorine, OH or C₁ -C₄ -alkoxy;L C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen, cyano, nitro; M hydrogen, C₁ -C₆ -alkyl, C₂ -C₆ -alkenyl, C₂ -C₆ -alkynyl, C₁ -C₄ -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C₁ -C₄ -alkoxy; halogen, cyano, nitro; X, R¹, R², R³, R⁴ and n are as given in claim
 1. 12. A herbicidal composition, comprising at least one hetaroyl derivative of the formula I as defined in claim 1 and additives.
 13. A method of controlling undesired plant growth, which comprises allowing a herbicidally active amount of a hetaroyl derivative of the formula I as defined in claim 1 to act on the plants or their habitat. 